Results 81 to 90 of about 3,258 (176)
New Concepts for Organocatalysis [PDF]
Organocatalysis, catalysis with low-molecular weight catalysts in which a metal is not part of the catalytic principle or the reaction substrate, can be as efficient and selective as metal- or biocatalysis.
List, B., B. List, Pan, S., S. C. Pan
core +1 more source
Recent Advances in Benzannulation Approaches to Aromatic Frameworks
This review summarizes benzannulation strategies reported over the past 5 years, highlighting recent advances that enable efficient access to structurally diverse and highly substituted arenes through both transition‐metal‐catalyzed and metal‐free approaches.
Heeeun Kim, Yonghoon Kwon
wiley +1 more source
Cupreines and cupreidines: an established class of bifunctional cinchona organocatalysts
Cinchona alkaloids with a free 6'-OH functionality are being increasingly used within asymmetric organocatalysis. This fascinating class of bifunctional catalyst offers a genuine alternative to the more commonly used thiourea systems and because of the ...
Laura A. Bryant +2 more
doaj +1 more source
Multistep Chemoenzymatic Cascade for the Synthesis of Chiral N‐Heterocycles
We describe a multistep cascade to access quinolizidine and indolizidine containing compounds that incorporates a transaminase to generate a reactive intermediate in situ and subsequent proline‐mediated Mannich‐aza‐Michael reaction for the construction of privileged aza‐bicyclic scaffolds.
Amber Barry +5 more
wiley +1 more source
The philosophy of organocatalysis is based on the utilization of organic compounds to catalyze organic transformations without the intervention of metals.
Giovanni W. Amarante, Fernando Coelho
doaj +1 more source
The Use of N-iPr-2,2'-bipyrrolidine Derivatives as Organocatalysts for Asymmetric Michael Additions
The recent rapid growth of organocatalysis has shown a new approach in organic chemistry and presents the obvious advantage in the avoidance of expensive and often toxic metals.
Sarah Mossé +2 more
doaj +1 more source
Non-covalent organocatalysis in asymmetric oxidative C(sp3)–H bond functionalization – broadening C–H bond coupling reactions [PDF]
Among the current huge development activities in C-H functionalization, asymmetric oxidative C(sp(3))-H bond coupling strategies have remained underrepresented. Beyond the initial examples using chiral metal complexes, the use of organocatalysis provides
Stockerl, Sebastian +1 more
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Asymmetric Counteranion-Directed Lewis Acid Organocatalysis. [PDF]
This work describes studies on asymmetric counteranion-directed Lewis acid organocatalysis. In the first part, the development of a catalytic asymmetric Hosomi–Sakurai reaction using BINOL-derived disulfonimides is described. Good to excellent yields and
van Gemmeren, M.
core
Searching for untrodden paths in organocatalysis territory [PDF]
In spite of the tremendous growth experienced by the field of asymmetric organocatalysis in the last decade, it is important to realize that we are still far away from having explored all of the possible pathways in organocatalysis ‘territory'; the ...
Xavier Companyó +12 more
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Chiral Lewis base (LB) organocatalysis has emerged as a powerful covalent catalysis concept which allows for highly selective asymmetric C–C and C-heteroatom bond formations.
Magdalena Piringer +5 more
doaj +1 more source

