Results 81 to 90 of about 3,258 (176)

New Concepts for Organocatalysis [PDF]

open access: yes, 2008
Organocatalysis, catalysis with low-molecular weight catalysts in which a metal is not part of the catalytic principle or the reaction substrate, can be as efficient and selective as metal- or biocatalysis.
List, B., B. List, Pan, S., S. C. Pan
core   +1 more source

Recent Advances in Benzannulation Approaches to Aromatic Frameworks

open access: yesChemistry – An Asian Journal, Volume 21, Issue 13, 14 July 2026.
This review summarizes benzannulation strategies reported over the past 5 years, highlighting recent advances that enable efficient access to structurally diverse and highly substituted arenes through both transition‐metal‐catalyzed and metal‐free approaches.
Heeeun Kim, Yonghoon Kwon
wiley   +1 more source

Cupreines and cupreidines: an established class of bifunctional cinchona organocatalysts

open access: yesBeilstein Journal of Organic Chemistry, 2016
Cinchona alkaloids with a free 6'-OH functionality are being increasingly used within asymmetric organocatalysis. This fascinating class of bifunctional catalyst offers a genuine alternative to the more commonly used thiourea systems and because of the ...
Laura A. Bryant   +2 more
doaj   +1 more source

Multistep Chemoenzymatic Cascade for the Synthesis of Chiral N‐Heterocycles

open access: yesChemCatChem, Volume 18, Issue 13, 14 July 2026.
We describe a multistep cascade to access quinolizidine and indolizidine containing compounds that incorporates a transaminase to generate a reactive intermediate in situ and subsequent proline‐mediated Mannich‐aza‐Michael reaction for the construction of privileged aza‐bicyclic scaffolds.
Amber Barry   +5 more
wiley   +1 more source

Reações de organocatálise com aminas quirais: aspectos mecanísticos e aplicações em síntese orgânica Organocatalysis reactions with chiral amines: mechanistic aspects and use on organic synthesis

open access: yesQuímica Nova, 2009
The philosophy of organocatalysis is based on the utilization of organic compounds to catalyze organic transformations without the intervention of metals.
Giovanni W. Amarante, Fernando Coelho
doaj   +1 more source

The Use of N-iPr-2,2'-bipyrrolidine Derivatives as Organocatalysts for Asymmetric Michael Additions

open access: yesCHIMIA, 2006
The recent rapid growth of organocatalysis has shown a new approach in organic chemistry and presents the obvious advantage in the avoidance of expensive and often toxic metals.
Sarah Mossé   +2 more
doaj   +1 more source

Non-covalent organocatalysis in asymmetric oxidative C(sp3)–H bond functionalization – broadening C–H bond coupling reactions [PDF]

open access: yes, 2016
Among the current huge development activities in C-H functionalization, asymmetric oxidative C(sp(3))-H bond coupling strategies have remained underrepresented. Beyond the initial examples using chiral metal complexes, the use of organocatalysis provides
Stockerl, Sebastian   +1 more
core   +1 more source

Asymmetric Counteranion-Directed Lewis Acid Organocatalysis. [PDF]

open access: yes, 2014
This work describes studies on asymmetric counteranion-directed Lewis acid organocatalysis. In the first part, the development of a catalytic asymmetric Hosomi–Sakurai reaction using BINOL-derived disulfonimides is described. Good to excellent yields and
van Gemmeren, M.
core  

Searching for untrodden paths in organocatalysis territory [PDF]

open access: yes, 2010
In spite of the tremendous growth experienced by the field of asymmetric organocatalysis in the last decade, it is important to realize that we are still far away from having explored all of the possible pathways in organocatalysis ‘territory'; the ...
Xavier Companyó   +12 more
core   +1 more source

Enantioselective α-heterofunctionalization reactions of catalytically generated C1-Lewis base enolates

open access: yesTetrahedron Chem
Chiral Lewis base (LB) organocatalysis has emerged as a powerful covalent catalysis concept which allows for highly selective asymmetric C–C and C-heteroatom bond formations.
Magdalena Piringer   +5 more
doaj   +1 more source

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