Results 41 to 50 of about 456,445 (341)

MCM-41-supported L-phenylalaninol as a chiral heterogeneous ligand in the enantioselective Kharasch-Sosnovsky reaction

open access: yesResults in Chemistry
In this study, L-phenylalaninol, synthesized from the reduction of naturally occurring L-phenylalanine, was immobilized on MCM-41. The resulting heterogeneous ligand was comprehensively characterized using various spectroscopic techniques, such as FT-IR,
Saadi Samadi   +3 more
doaj   +1 more source

Flow chemistry in the multi-step synthesis of natural products

open access: yesGreen Synthesis and Catalysis, 2022
The total synthesis of natural products is constantly facing many challenges derived from the complexed chemical structures, the lengthy synthetic routes, the time-consuming workup procedures and the large environmental footprint. In the past two decades,
Li Wan   +5 more
doaj   +1 more source

Synthesis and photophysical properties of new reactive fluorophenanthrenes

open access: yesComptes Rendus. Chimie, 2020
A series of six new suitably functionalized fluorophenanthrene derivatives were synthesized through a simple procedure, making use of inexpensive starting materials under mild conditions.
Hajri, Amira K.   +3 more
doaj   +1 more source

Asymmetric oxidation of sulfides [PDF]

open access: yes, 2016
This review discusses synthesis of enantiopure sulfoxides through the asymmetric oxidation of prochiral sulfides. The use of metal complexes to promote asymmetric sulfoxidation is described in detail, with a particular emphasis on the synthesis of ...
Ford, Alan   +2 more
core   +1 more source

Progress in Stereoselective Haloamination of Olefins

open access: yesMolecules
The regio- and stereoselective adjacent bifunctionalization of olefins with amine and halogen groups can be effectively accomplished through catalytic haloamination methods.
Guo Zhong, Jiayu Zhou, Bin Cui, Hui Sun
doaj   +1 more source

Synthesis of enantioenriched sulfoxides [PDF]

open access: yes, 2010
This review discusses strategies for the asymmetric synthesis of sulfoxides, compounds with many applications in stereoselective synthesis and in some cases with pharmaceutical application.
Kelly, Padraig   +3 more
core   +1 more source

Chiral amido-oxazoline functionalized MCM-41: A sustainable heterogeneous catalyst for enantioselective Kharasch–Sosnovsky and Henry reactions

open access: yesHeliyon
In this study, a series of chiral amido-oxazoline ligands was synthesized with a primary focus on immobilizing the most effective ligands on MCM-41 mesoporous material.
Niloofar Tavakoli   +5 more
doaj   +1 more source

Development of non-nucleoside reverse transcriptase inhibitors (NNRTIs): our past twenty years

open access: yesActa Pharmaceutica Sinica B, 2020
Human immunodeficiency virus (HIV) is the primary infectious agent of acquired immunodeficiency syndrome (AIDS), and non-nucleoside reverse transcriptase inhibitors (NNRTIs) are the cornerstone of HIV treatment.
Chunlin Zhuang   +3 more
doaj   +1 more source

Development of diverse adjustable axially chiral biphenyl ligands and catalysts

open access: yesiScience, 2023
Summary: Development of highly efficient and practical chiral ligands and catalysts is an eternal theme in asymmetric synthesis. Here, we report the design, synthesis, and evaluation of a new kind of adjustable axially chiral biphenyl ligands and ...
Jiyang Jie   +3 more
doaj   +1 more source

Heterogenisation of ketone catalysts within mesoporous supports for asymmetric epoxidation

open access: yes, 2013
The synthesis of the first mesoporous silica (150 Ã…) anchored carbohydrate-derived chiral ketone is described. This new heterogeneous catalyst has been shown to be effective in the asymmetric epoxidation of olefins by oxone.
Adam   +60 more
core   +1 more source

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