Results 61 to 70 of about 17,975 (276)

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

Chemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis, Kyriakos D. Nikopoulos, Ioannis N. Lykakis   +2 more
wiley   +1 more source

Chemical Upcycling of Nitrile Butadiene Rubbers to Polyamines and Polyols by Chemoselective Catalytic Hydrogenation

Angewandte Chemie, Volume 138, Issue 18, 27 April 2026.
We demonstrate here the transformation of NBR (Nitrile butadiene rubber) including post‐consumer waste sourced from nitrile gloves and o‐rings into polyamines and polyols via ruthenium catalyzed hydrogenation. ABSTRACT We report here two new approaches for the chemical recycling/upcycling of nitrile butadiene rubber (NBR) to make either polyamines or ...
Alejandra Sophia Lozano Perez, Raymundo Marcial‐Hernandez, Harini Sampathkumar, Oluchi Emenike, Ketan Pancholi, Claire N. Brodie, Daniel M. Dawson, Amit Kumar   +7 more
wiley   +2 more sources

Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis

Beilstein Journal of Organic Chemistry, 2014
The Co(II) complex of a new D2-symmetric chiral porphyrin 3,5-DiMes-QingPhyrin, [Co(P6)], can catalyze asymmetric aziridination of alkenes with bis(2,2,2-trichloroethyl)phosphoryl azide (TcepN3) as a nitrene source.
Jingran Tao, Li-Mei Jin, X. Peter Zhang
doaj   +1 more source

New vibrational assignments for the nu1 to nu17 vibrational modes of aziridine and first analysis of the high resolution infrared spectrum of aziridine between 720 cm-1 and 1050 cm-1 [PDF]

, 2011
International audienceFourier transform spectra of aziridine (C2H4NH) were recorded at high resolution (0.002 or 0.003 cm-1) in the 600-1750 and 1750-4000 cm-1 regions, using a Bruker IFS125HR spectrometer, located at the LISA facility in Creteil.
Demaison, Jean, FLAUD, Jean Marie, Guillemin, Jean-Claude, Kwabia-Tchana, Fridolin, Ngom, Abib, Ngom, Malick, Perrin, Agnes   +6 more
core   +4 more sources

Strain Release of 1‐Azabicyclo[1.1.0]butanes as a Gateway to Highly Functionalized Azetidines: New Strategies and Structural Motifs

Chemistry – A European Journal, EarlyView.
Over the past decade, the interest in azetidines has continuously risen, by virtue of their highly appealing pharmaceutical properties. Monocyclic, spirocyclic, and bridged azetidines can be accessed by leveraging 1‐azabicyclo[1.1.0]butanes as precursors.
Yuri Gelato, Philipp Natho, Marco Colella, Renzo Luisi   +3 more
wiley   +1 more source

Y(OTf)₃-Salazin-Catalyzed Asymmetric Aldol Condensation

Molecules
The chiral aziridine-containing vicinal iminophenol tridentate ligands (named salazins) are a class of readily prepared chiral ligands from enantiopure aziridines and salicylaldehydes.
Chengzhuo Wang, Ning Chen, Zhanhui Yang, Jiaxi Xu   +3 more
doaj   +1 more source

Microwave-promoted total synthesis of N-(α-hydroxybenzyl)formamides using DMSO/H2O under neutral conditions

Green Chemistry Letters and Reviews, 2016
A total synthesis route toward N-(α-hydroxybenzyl)formamides by microwave-assisted reaction of dichloroaziridines and aqueous dimethyl sulfoxide is described. The corresponding products were obtained in excellent yields with reduced reaction times.
Khadijeh Rabiei, Hossein Naeimi
doaj   +1 more source

A Mild and Regioselective Ring-Opening of Aziridines with Acid Anhydride Using TBD or PS-TBD as a Catalyst

Molecules, 2015
The ring-opening of N-tosylaziridines with various acid anhydrides catalyzed by 5 mol % of 1,5,7-triazabicyclo[4,4,0]dec-5-ene (TBD) afforded the corresponding β-amino esters in excellent yields under mild reaction conditions. Polymer-supported catalyst,
Satoru Matsukawa, Yasutaka Mouri
doaj   +1 more source

Optically active aziridine esters by nucleophilic addition of nitrogen heterocycles to a chiral 2H-azirine-2-carboxylic ester [PDF]

, 2003
Chiral enriched ethyl 3-methyl-2H-azirine-2-carboxylate acts as an efficient alkylating agent for a variety of five membered aromatic nitrogen heterocycles.Fundação para a Ciência e Tecnologia - POCTI/32723/QUI/2000 ...
Alves, M. José, Fortes, A. Gil, Gonçalves, Luís F. F. F.   +2 more
core   +1 more source

Strong Nonradiative Recombination Induced by Pronounced Lone‐Pair Electron Expression Following Deprotonation in Aziridinium Lead Iodide Perovskites

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The transition from linear to cyclic organic cations promotes deprotonation and activates VH(N) defects with pronounced lone‐pair electron activity, thereby inducing severe local distortions and highly efficient nonradiative recombination centers. This work unveils a direct structure–defect–performance correlation and proposes design strategies for the
Qingshan Bao, Linyu Bai, Honghe Zhao, Yanting Qin, Xian Zhao, Yanlu Li   +5 more
wiley   +1 more source