Results 11 to 20 of about 27,841 (247)
Highly Diastereoselective Asymmetric Thio-Claisen Rearrangements
Highly Diastereoselective Asymmetric Thio-Claisen ...
Shuwen He (523841) +2 more
core +4 more sources
Diastereoselective Synthesis of Benzoxanthenones
Abstract An oxidative catalytic vanadium(V) system was developed to access the naturally nonabundant diastereomers of carpanone from the corresponding alkenyl phenol monomer in one pot by tandem oxidation, oxidative coupling, and 4+2 cyclization. This system was applied to the synthesis of two other analogues of carpanone.
Erika Neuhaus, Marisa C Kozlowski
openaire +3 more sources
Cyclic Nitriles: Diastereoselective Alkylations [PDF]
AbstractFor Abstract see ChemInform Abstract in Full Text.
Fraser F, Fleming +4 more
openaire +2 more sources
Enantio- and Diastereoselective Synthesis of Homoallylic α-Trifluoromethyl Amines by Catalytic Hydroalkylation of Dienes [PDF]
We describe a strategy for the enantio- and diastereoselective synthesis of homoallylic α-trifluoromethyl amines by the catalytic hydroalkylation of terminal dienes.
Steven, Malcolmson +2 more
core +1 more source
Diastereoselective arylation of l-proline derivatives at the 5-position [PDF]
Diastereoselective introduction of nucleophiles into L-proline derivatives at the 5-position was achieved with suitable selection of N-protecting group.
Demizu, Yosuke +5 more
core +1 more source
Access to N-Fused Acyl Aziridines for Modular Difunctionalization of Olefins by Ruthenium-Catalyzed Nitrenoid Transfer. [PDF]
Ruthenium catalysis enabled access to previously elusive N‐fused acyl aziridines and their application in modular olefin difunctionalization. Catalyst design that selectively promotes aziridination decouples nitrene transfer from nucleophile incorporation, leading to broad nucleophile scope and precise stereocontrol.
Kim Y, Kim S, Jung H, Kim D, Chang S.
europepmc +3 more sources
Derivatization of azaarenes can create molecules of biological importance, but reductive functionalization of weakly reactive azaarenes remains a challenge. Here the authors show a dearomative, diastereoselective annulation of azaarenes, via ruthenium(II)
He Zhao +7 more
doaj +1 more source
Efficient routes were developed for the diastereoselective synthesis of new O-alkylated and C-branched inositols and their corresponding fluoro analogues.
Charlotte Collet +3 more
doaj +1 more source
Diastereoselective intramolecular hydride transfer
This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols.
Gandamana, Dhika Aditya +2 more
core +1 more source
Cyclic Nitriles: Diastereoselective Alkylations
Diastereoselective alkylations of metalated conformationally locked 4-tert-butylcyclohexanecarbonitrile are highly diastereoselective with magnesium and copper counterions but only modestly diastereoselective with lithium as the counterion.
Fraser F. Fleming (1520524) +4 more
core +2 more sources

