Ti-MCM-41 materials synthesised at room temperature as catalysts for cyclisation of (±)-citronellal” [PDF]
In the present work we extend the applicability of those Ti-MCM-41 materials, as heterogeneous catalysts, to produce an important intermediate, isopulegol, from the cyclisation of citronellal. The use of this kind of materials appears to be a good option
Carrott, Manuela+5 more
core
Stereoselective synthesis of hydroxylated 3-aminoazepanes using a multi-bond forming, three-step tandem process [PDF]
A multi-bond forming, three-step tandem process involving a palladium(II)-catalysed Overman rearrangement and a ring closing metathesis reaction has been utilised for the efficient synthesis of a 2,3,6,7-tetrahydro-3-amidoazepine.
Ahmad+63 more
core +1 more source
Catalytic Diastereoselective Petasis Reactions [PDF]
AbstractPetasis reaction of boronates, protected α‐hydroxy aldehydes and amines is described.
Stuart L. Schreiber+3 more
openaire +4 more sources
An efficient synthesis of the guaiane sesquiterpene (−)-isoguaiene by domino metathesis
(−)-Isoguaiene was prepared from (S)-citronellal in only 9–10 steps with good overall yields. Either a trienyne or a dienediyne metathesis and highly diastereoselective organocatalytic Michael additions of aldehydes derived from (S)-citronellal served as
Yuzhou Wang+3 more
doaj +1 more source
Diastereoselective reactions of enolates [PDF]
Abstract
Dietmar Galle+3 more
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Crystal and molecular structure of bis(8-phenylmenthyl) 2-(2-methyl-5-oxo-3-cyclohexen-1-yl)propandioate, C\u3csub\u3e42\u3c/sub\u3eH\u3csub\u3e54\u3c/sub\u3eO\u3csub\u3e5\u3c/sub\u3e• CH\u3csub\u3e3\u3c/sub\u3eCN [PDF]
The X-ray crystal structure of the title compound, as crystallized from acetonitrile-water was determined. The relative stereochemistry of the cyclohexenone ring with respect to the 8-phenylmenthyl esters was determined.
Bennett, Dennis W.+4 more
core +1 more source
Summary: Chiral syn-1,3-diols are fundamental structural motifs in many natural products and drugs. The traditional Narasaka-Prasad diastereoselective reduction from chiral β-hydroxyketones is an important process for the synthesis of these ...
Guanxin Huang+7 more
doaj
Synthesis of dihydrofurans using nano-CuFe2O4@Chitosan
An efficient multi-component synthesis of dihydrofurans is described by a one-pot condensation reaction of 2,4′-dibromoacetophenone, aromatic aldehydes and dimedone using nano-CuFe2O4@Chitosan under reflux conditions in ethanol.
Javad Safaei-Ghomi+1 more
doaj
Total Asymmetric Synthesis of Glycomimetics and Polypropionates of Biological Interest
Using readily available chiral auxiliaries such as (+)- and (?)-camphanic acid, (R,R)- and (S,S)-tartaric acid derivatives (e.g. RADO(R)-COCl, SADO(R)-COCl) efficient diastereoselective syntheses of rare sugars and glycomimetics have been ...
Pierre Vogel
doaj +1 more source
A Shortened Synthesis of Optically Pure Tricarbonyl[methyl (2E,4E)-6-oxo-2,4-hexadienoate]Iron Leading to Improved Yield [PDF]
The (+)- and (–)-enantiomers of tricarbonyl[methyl (2E,4E)-6-oxo-2,4-hexadienoate]iron are prepared in 4 steps from commercially available hexadienal (26% and 25% yields, respectively)
Donaldson, William+2 more
core +2 more sources