Half-Sandwich d6-Metal (CoIII, RhIII, IrIII, RuII)-Catalyzed Enantioselective C–H Activation
Pu-Fan Qian+4 more
doaj +1 more source
Deconstructive Radical‐Radical Coupling for Programmable Remote Acylation
Dicarbonyl compounds are structural motifs that have been extensively utilized in synthetic chemistry, and their downstream transformations have proven valuable in synthesizing numerous heterocycles. Conventional methods for accessing such compounds include the Stetter reaction, the Michael reaction, and Friedel‐Crafts acylation.
Karl Scheidt, Jing Cao, Cullen Schull
wiley +1 more source
Pd-Catalyzed asymmetric allylic amination with isatin using a P,olefin-type chiral ligand with C-N bond axial chirality. [PDF]
Akimoto N+5 more
europepmc +1 more source
Enzyme-catalyzed C(sp<sup>3</sup>)-H aminations for the highly enantioselective construction of chiral 2-oxazolidinones. [PDF]
Gao H, Li M, Zheng G.
europepmc +1 more source
Hexafluoroisopropanol Solvent Effects on Enantioselectivity of Dirhodium Tetracarboxylate-Catalyzed Cyclopropanation. [PDF]
Alturaifi TM+8 more
europepmc +1 more source
Isothiourea catalysed enantioselective generation of point and axially chiral iminothia- and iminoselenazinanones. [PDF]
Nimmo AJ+6 more
europepmc +1 more source
2-(Cyanomethyl)benzimidazole Derivatives as 1,3-Dicarbonyl Analogues for a Kinetically Controlled Diastereo- and Enantioselective Mannich-Type Reaction Catalyzed by Chiral Phosphoric Acid. [PDF]
Ye H+7 more
europepmc +1 more source
Atropisomeric [(diphosphine)Au2Cl2] complexes and their catalytic activity towards asymmetric cycloisomerisation of 1,6-enynes [PDF]
Barreiro, EM+3 more
core +2 more sources
Catalytic asymmetric 1,3‐dipolar cycloadditions (1,3‐DCA) using iminoesters as ylide precursors offer a powerful approach to accessing stereochemically complex, biologically relevant pyrrolidines. While previous studies have already achieved impressive stereoselectivities, catalytic productivity remains a challenge, with turnover numbers (TON ...
Adrian Bürstner+13 more
wiley +1 more source