Results 171 to 180 of about 39,817 (294)

Half-Sandwich d6-Metal (CoIII, RhIII, IrIII, RuII)-Catalyzed Enantioselective C–H Activation

open access: yesSynOpen, 2023
Pu-Fan Qian   +4 more
doaj   +1 more source

Deconstructive Radical‐Radical Coupling for Programmable Remote Acylation

open access: yesAngewandte Chemie International Edition, Accepted Article.
Dicarbonyl compounds are structural motifs that have been extensively utilized in synthetic chemistry, and their downstream transformations have proven valuable in synthesizing numerous heterocycles. Conventional methods for accessing such compounds include the Stetter reaction, the Michael reaction, and Friedel‐Crafts acylation.
Karl Scheidt, Jing Cao, Cullen Schull
wiley   +1 more source

Hexafluoroisopropanol Solvent Effects on Enantioselectivity of Dirhodium Tetracarboxylate-Catalyzed Cyclopropanation. [PDF]

open access: yesJ Am Chem Soc
Alturaifi TM   +8 more
europepmc   +1 more source

Tunable Endo/Exo Selectivity in Direct Catalytic Asymmetric 1,3‐Dipolar Cycloadditions with Polyfunctional Lewis Acid / Azolium‐Aryloxide Catalysts

open access: yesAngewandte Chemie International Edition, Accepted Article.
Catalytic asymmetric 1,3‐dipolar cycloadditions (1,3‐DCA) using iminoesters as ylide precursors offer a powerful approach to accessing stereochemically complex, biologically relevant pyrrolidines. While previous studies have already achieved impressive stereoselectivities, catalytic productivity remains a challenge, with turnover numbers (TON ...
Adrian Bürstner   +13 more
wiley   +1 more source

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