Organocatalytic atroposelective <i>de novo</i> construction of monoaxially and 1,4-diaxially chiral fused uracils with potential antitumor activity. [PDF]
Ren Y+6 more
europepmc +1 more source
Covalent immobilization of the Jacobsen catalyst on mesoporous phenolic polymer : a highly enantioselective and stable asymmetric epoxidation catalyst [PDF]
Bogaerts, Thomas+7 more
core +2 more sources
We report two chiral NCS compounds, (R)‐Sb and (S)‐Sb, featuring aligned Sb3⁺ lone pairs and hydrogen‐bonded [SbOF₃] polyhedra with 4‐hydroxyphenylglycine. These structures exhibit strong SHG (2.6 × KDP), a wide band gap (4.19 eV), and suitable birefringence (0.184@546.1 nm), highlighting the potential of Sb3⁺‐based hybrids for NLO applications ...
Seoyeon Choi, Kang Min Ok
wiley +1 more source
Precise construction of spiro stereocenters <i>via</i> enantioselective radical addition through modulating photocatalysis from redox to energy transfer. [PDF]
Liu F+5 more
europepmc +1 more source
Abstract Fishing waste and byproducts, whether naturally occurring or from industrial processing, are important sources of high‐value compounds. Fertilizers, biomaterials, cosmetics, biolubricants, and biodiesel are some of the substances that can be obtained from these residues. The objective of this study was to conduct a theoretical and experimental
Patrick da Silva Sousa+7 more
wiley +1 more source
Photoinduced copper-catalysed enantioselective amination of allylic and propargylic C-H bonds. [PDF]
Dai L+4 more
europepmc +1 more source
α‐Azaaryl carbonyl derivatives in stereodivergent catalytic reactions
This review highlights recent progress in the catalytic synthesis of chiral azaarenes, focusing on α‐azaaryl carbonyl derivatives as versatile precursors. By leveraging chiral Lewis acid catalysis, stereodivergent reactions with diverse electrophiles enable precise construction of multi‐stereogenic azaarenes, offering new opportunities for advanced ...
Ilwoo Song+3 more
wiley +1 more source
Performance-Enhancing Asymmetric Catalysis Driven by Achiral Counterion Design. [PDF]
Deng Z+5 more
europepmc +1 more source
Cp*Co(III)‐catalyzed C–H functionalization of bioactive heterocyclic motifs
Directed carbon–hydrogen bond functionalization of biologically active scaffolds is attractive as it enables the selective modification of sophisticated structures, enhancing the efficiency of drug development by adopting diverse functional groups. This review summarizes recent advances in cobalt‐catalyzed C–H functionalizations of bioactive motifs ...
Yeongmi Park+3 more
wiley +1 more source
Enantioselective synthesis of spiro[indoline-3,1'-pyrazolo[1,2-<i>b</i>]phthalazine] derivatives <i>via</i> an organocatalytic three-component cascade reaction. [PDF]
Song L, Sun Y, An R, Wang L, Jin Y.
europepmc +1 more source