Results 71 to 80 of about 39,817 (294)

Expanding the set of rhodococcal Baeyer–Villiger monooxygenases by high-throughput cloning, expression and substrate screening [PDF]

open access: yes, 2012
To expand the available set of Baeyer–Villiger monooxygenases (BVMOs), we have created expression constructs for producing 22 Type I BVMOs that are present in the genome of Rhodococcus jostii RHA1.
A Alfieri   +38 more
core   +4 more sources

Halide Perovskite Photocatalysts for Clean Fuel Production and Organic Synthesis: Opportunities and Challenges

open access: yesAdvanced Materials, EarlyView.
This review provides the state‐of‐the‐art overview of halide perovskite‐based photocatalysts for hydrogen production from water and halogen acid solutions, CO2 reduction into value‐added chemicals, and organic chemical transformations. Different types of halide perovskite photocatalysts and their relative efficiencies for hydrogen generation and CO2 ...
Siddharth Singh   +8 more
wiley   +1 more source

A Chiral Metal—Organic Framework Prepared on Large-Scale for Sensitive and Enantioselective Fluorescence Recognition

open access: yesMolecules, 2023
MOF-based luminescent sensors have garnered considerable attention due to their potential in recognition and discrimination with high sensitivity, selectivity, and fast response in the last decades.
Xin-Mei Zhang   +8 more
doaj   +1 more source

Mode‐dependent Far‐field Radiation of Circularly Polarized Light by a Single Plasmonic Nanohelix

open access: yesAdvanced Optical Materials, Volume 13, Issue 8, March 13, 2025.
The numerical simulations explored the chiroptical response and far‐field radiation behaviors of single plasmonic nanoantennas transitioning into helical structures. This study highlights the ability of these plasmonic nanohelices to regulate the far‐field directionality of radiation power and circular polarization in plasmon‐exciton coupled systems ...
Yiou Cui   +10 more
wiley   +1 more source

Redesign of a short-chain dehydrogenase/reductase for asymmetric synthesis of ethyl (R)-2-hydroxy-4-phenylbutanoate based on per-residue free energy decomposition and sequence conservatism analysis

open access: yesGreen Synthesis and Catalysis, 2020
As an important building block for the synthesis of angiotensin-converting enzyme inhibitors, ethyl (R)-2-hydroxyl-4-phenylbutanoate [(R)-HPBE] has attracted increasing attention.
Bingmei Su   +7 more
doaj  

Efficient Improving the Activity and Enantioselectivity of Candida rugosa Lipase for the Resolution of Naproxen by Enzyme Immobilization on MCM-41 Mesoporous Molecular Sieve [PDF]

open access: yesInternational Journal Bioautomation, 2015
Lipase from Candida rogusa was immobilized on MCM-41 mesoporous molecular sieves in a trapped aqueous-organic biphase system for the resolution of racemic naproxen methyl ester.
Ying Chen, Yi Xu, Xiao-mei Wu
doaj  

Oligomerization of optically active N-(4-hydroxyphenyl)mandelamide in the presence of β-cyclodextrin and the minor role of chirality

open access: yesBeilstein Journal of Organic Chemistry, 2014
The oxidative oligomerization of a chiral mandelamide derivative (N-(4-hydroxyphenyl)mandelamide, 1) was performed in the presence of horseradish peroxidase, laccase and N,N'-bis(salicylidene)ethylenediamine-iron(II) to obtain chiral oligophenols 2.
Helmut Ritter   +2 more
doaj   +1 more source

Plasmonic elliptical nanoholes for chiroptical analysis and enantioselective optical trapping [PDF]

open access: yesarXiv, 2021
A simple yet effective achiral platform using elliptical nanoholes for chiroptical analysis is demonstrated. Under linearly polarized excitation, an elliptical nanohole in a thin gold film can generate a localized chiral optical field for chiroptical analysis and simultaneously serve as a near-field optical trap to capture dielectric and plasmonic ...
arxiv  

Biocatalytic Route to Chiral Precursors of β-Substituted-γ-Amino Acids [PDF]

open access: yes, 2011
In this work, we utilized commercial lipases (from Thermomyces lanuginosa, Rhizopus delemar, and Mucor miehei) as biocatalysts for the efficient synthesis of precursors of β-substituted-γ-amino acids.
Martinez, Carlos A., Mukherjee, Herschel
core   +2 more sources

Enantioselective Synthesis of (−)‐Halenaquinone

open access: yesAngewandte Chemie International Edition, 2018
AbstractThe efficient, 12–14 step (LLS) total synthesis of (−)‐halenaquinone has been achieved. Key steps in the synthetic sequence include: (a) proline sulfonamide‐catalyzed, Yamada–Otani reaction to establish the C6 all‐carbon quaternary stereocenter, (b) multiple, novel palladium‐mediated oxidative cyclizations to introduce the furan moiety, and (c) 
Subir Goswami   +5 more
openaire   +4 more sources

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