Results 141 to 150 of about 169,803 (413)

Synthesis of Oxygen Heterocycles via Aromatic C-O Bond Formation Using Arynes

open access: yesMolecules, 2015
Most of the synthetic approaches to the benzo-fused heterocycles containing an oxygen atom have involved the use of phenol derivatives as a starting material.
Hideto Miyabe
doaj   +1 more source

Regioselective reactions of 3,4-pyridynes enabled by the aryne distortion model. [PDF]

open access: yes, 2013
The pyridine heterocycle continues to play a vital role in the development of human medicines. More than 100 currently marketed drugs contain this privileged unit, which remains highly sought after synthetically. We report an efficient means to access di-
Garg, Neil K, Goetz, Adam E
core  

Recent Developments in Radical Mediated Synthesis of Organostannanes.

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract The present review aims to provide an overview of the recent developments in the preparation of aryl‐ or alkenyl stannanes via carbon‐ and tin‐centered radicals enabling chemists to synthesize organostannyl derivatives with high efficiency and under mild conditions.
Qianhang Ren   +4 more
wiley   +1 more source

Nine-Membered Benzofuran-Fused Heterocycles: Enantioselective Synthesis by Pd-Catalysis and Rearrangement via Transannular Bond Formation.

open access: yesJournal of the American Chemical Society, 2017
The first enantioselective formal [5+4] cycloaddition is realized under palladium catalysis to deliver benzofuran-fused nine-membered rings. These medium-sized heterocycles and derivatives undergo unique rearrangements induced by transannular bond ...
Zi-Qiang Rong   +8 more
semanticscholar   +1 more source

Cycloalkenopyridines by ring transformations of diazines and triazines [PDF]

open access: yes, 2008
This paper is a short review on the synthesis of 2,3-cycloalkenopyridines and 3,4-cycloalkenopyridines by inter- and intra-molecular ...
Plas, H.C., van der
core   +3 more sources

Synthesis of Polysubstituted Naphthalenes via Metal‐Free Borylative Cyclization of o‐Alkynylstyrenes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract A selective, metal‐free method for the synthesis of boron‐functionalized polysubstituted naphthalenes via BCl3‐mediated cyclization of α‐substituted o‐alkynylstyrenes is described. The reaction exhibits broad substrate scope, tolerating various groups such as ethers, sulfides and halogens, and delivers high yields under mild conditions, even ...
Marcos Humanes   +2 more
wiley   +1 more source

Development of Hydrofluoroolefin (HFO)‐based direct O‐fluoroalkenylation of phenols targeting tyrosine conjugation

open access: yesAdvanced Synthesis &Catalysis, Accepted Article.
Methodology for direct fluoroalkenylation of phenolic OH function was developed using a fluorinated electrophilic reagent derived from HFO1234ze gas. Besides various functionalized phenols, tyrosine and tyrosine‐based peptides were successfully conjugated under the optimized reaction conditions.
Rihárd Sisa   +2 more
wiley   +1 more source

Thermally Stimulated Luminescence and Current in new heterocyclic materials for Organic field transistors and organic light emitting diodes [PDF]

open access: yesarXiv, 2007
The present work is focused on theoretical and experimental study of localised levels in organic materials suitable for light-emitting devices and field effect transistors by means of thermal techniques. In our work we focused on low molecular compounds as well as on polymers, especially of two classes of materials: oxadiazoles and quinoxalines.
arxiv  

Small Heterocyclic Molecule as Multistate Transistor: A Quantum Many-body Approach [PDF]

open access: yesarXiv, 2020
Weakly coupled molecular junctions are an active and important field of research as they exhibit various non-linear transport phenomena. We have investigated the carrier transport through weakly coupled B2C2N2H6 molecules using quantum many-body approach coupled with kinetic (master) equations. Interestingly, various types of non-linear current-voltage
arxiv  

A Multi‐Objective Molecular Generation Method Based on Pareto Algorithm and Monte Carlo Tree Search

open access: yesAdvanced Science, EarlyView.
Pareto Monte Carlo Tree Search Molecular Generation (PMMG), a molecular generation approach leveraging Monte Carlo Tree Search (MCTS) and Pareto algorithm, efficiently explores the Pareto front in high‐dimensional objective spaces for multi‐objective drug design.
Yifei Liu   +12 more
wiley   +1 more source

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