Results 51 to 60 of about 2,106 (176)

Tempol moderately extends survival in a hSOD1(G93A) ALS rat model by inhibiting neuronal cell loss, oxidative damage and levels of non-native hSOD1(G93A) forms. [PDF]

PLoS ONE, 2013
Amyotrophic lateral sclerosis (ALS) is a fatal neurodegenerative disease characterized by the progressive dysfunction and death of motor neurons by mechanisms that remain unclear.
Edlaine Linares, Luciana V Seixas, Janaina N dos Prazeres, Fernando V L Ladd, Aliny A B L Ladd, Antonio A Coppi, Ohara Augusto   +6 more
doaj   +1 more source

Embedding a Dinuclear Ru─Pt Photocatalyst Into Polyampholytic Graft Copolymer Matrix Enables Prolonged Hydrogen Evolution While Allowing Catalyst Repair

Chemistry – A European Journal, EarlyView.
A unimolecular polyampholytic graft copolymer matrix provides a protective confinement for an electrostatically embedded tetrapyridophenazine‐bridged heterodinuclear Ru‐Pt hydrogen evolving photocatalyst. The matrix slows the degradation kinetics of the catalyst and at the same time does not hinder its repair by ammonium persulfate.
Yurii Utievskyi, Alexander K. Mengele, Mariet Puthanagady, Nikita Vashistha, Linda Zedler, Christof Neumann, Marius Müßler, Andrey Turchanin, Benjamin Dietzek‐Ivanšić, Sven Rau, Felix H. Schacher   +10 more
wiley   +1 more source

Synthesis and characterization of amphiphilic nitroxide 1,1,3,3–tetraethylisoindoline–2–oxyl–5–sodium sulfonate (TEIOSNa)

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract The synthesis and characterization of an amphiphilic nitroxide to be used as a controlling agent in a nitroxide‐mediated living radical polymerization in aqueous dispersion media is presented. In the first stage of nitroxide synthesis (phthalimide protection), two reaction methods were employed: traditional and microwave.
Enrique García‐Leal, Martha Eugenia Albores Velasco, René O. Vargas, Rubén Mil‐Martínez   +3 more
wiley   +1 more source

Spin Transition in the Cu(hfac)₂ Complex with (4-Ethylpyridin-3-yl)-Substituted Nitronyl Nitroxide Caused by the “Asymmetric” Structural Rearrangement of Exchange Clusters in the Heterospin Molecule

Crystals, 2019
Methods for the synthesis of binuclear [Cu(hfac)2LEt]2 and tetranuclear [[Cu(hfac)2]4(LEt)2] heterospin compounds based on copper hexafluoroacetylacetonate [Cu(hfac)2] and 2-(4-ethylpyridin-3-yl)-4,5-bis(spirocyclopentyl)-4,5-dihydro-1H-imidazole-3-oxide-
Natalia Artiukhova, Galina Romanenko, Gleb Letyagin, Artem Bogomyakov, Sergey Veber, Olga Minakova, Marina Petrova, Vitaliy Morozov, Victor Ovcharenko   +8 more
doaj   +1 more source

Circular and Bio‐Sourced Polymers for Energy Applications: Natural Feedstocks, Recycling, and Upcycling Routes

EcoEnergy, EarlyView.
This review provides a critical comparative analysis of circular and bio‐sourced polymers for energy storage, systematically evaluating natural feedstocks alongside recycling and upcycling strategies for battery components. Key structure–property–performance relationships and inherent trade‐offs between sustainability metrics and electrochemical ...
Priyank Sinha, Amul Jain, Koushik Mahata, Sanjib Banerjee   +3 more
wiley   +1 more source

Assembly of Imidazolyl-Substituted Nitronyl Nitroxides into Ferromagnetically Coupled Chains

Crystals, 2019
New nitronyl nitroxides, namely, 2-(4,5-dimethylimidazol-2-yl)- and 2-(4,5-dichloroimidazol-2-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyl, were prepared in crystalline form.
Vasily Romanov, Irina Bagryanskaya, Nina Gritsan, Dmitry Gorbunov, Yulia Vlasenko, Mehman Yusubov, Elena Zaytseva, Dominique Luneau, Evgeny Tretyakov   +8 more
doaj   +1 more source

nitroxides

, 2014
Citation: 'nitroxides' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.N04171 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

From Mn(II)3 to Mn(IV)3: Controlled Multielectron Oxidation and Hydrocarbon Oxygenation Within a 7‐Dipy Trinuclear Scaffold

Journal of the Chinese Chemical Society, EarlyView.
A trinuclear manganese complex supported by the 7‐Dipy scaffold undergoes controlled multielectron oxidation from Mn(II)3 to high‐valent Mn(IV)3 states. Spectroscopic signatures, including 16‐line and geff ≈ 5 EPR features, reveal stepwise redox accumulation. The oxidized Mn3 cluster mediates efficient oxygen‐atom transfer to strong CH bonds, enabling
Yu‐Hsuan Chen, Peter Ping‐Yu Chen
wiley   +1 more source

Mechanical Properties and Testing Strategies for Two‐Photon Lithography: A Review of Current Practices and Emerging Challenges

Laser &Photonics Reviews, EarlyView.
Two‐photon lithography enables the fabrication of complex 3D microstructures with tunable mechanical properties spanning from soft hydrogels to rigid hybrid networks. This review summarizes how material composition, printing parameters, and post‐processing govern stiffness and viscoelasticity, highlighting advanced characterization methods and emerging
Dalila Fontana, Edoardo Rossi, Marco Sebastiani, Edoardo Bemporad, Angelo Accardo, Alberto Rainer, Enrico D. Lemma   +6 more
wiley   +1 more source

Reprocessable Vitrimers From Post‐Consumer Polyolefin Blends: Elucidating Phase‐Selective Dynamic Networks

Macromolecular Rapid Communications, EarlyView.
Reactive melt extrusion utilizing nitroxide‐mediated silyl ether chemistry transforms post‐consumer high‐density polyethylene and polypropylene blends into robust vitrimers. Featuring highly phase‐selective crosslinking, these upcycled materials combine thermoset‐like dimensional stability at elevated temperatures with dynamic melt‐reprocessability ...
Subhaprad Ash, Rishi Sharma, Li Xie, Muhammad Rabnawaz   +3 more
wiley   +1 more source