Results 91 to 100 of about 14,808 (226)
(E)-4-(3-Phenylisoxazol-5-yl)but-3-en-2-one
(E)-4-(3-Phenylisoxazol-5-yl)but-3-en-2-one was synthesized via the oxidative ring opening reaction of 2-(5-methylfuran-2-yl)-1-phenylethanone oxime, followed by the iodine mediated isomerization.
Nattawut Sawengngen +2 more
doaj +1 more source
Access to highly substituted oxazoles by the reaction of α-azidochalcone with potassium thiocyanate
The reactivity of α-azidochalcones has been explored for the preparation of highly substituted oxazoles via a 2H-azirine intermediate. The azidochalcones, when treated with potassium thiocyanate in the presence of potassium persulfate, lead to 2,4,5 ...
Mysore Bhyrappa Harisha +4 more
doaj +1 more source
The Cyclisation of l-Aryl-2-Benzamidoalkan-l-Ols to 4,5-DihydroOxazoles or Isoquinolines [PDF]
The cyclisation of several N-benzoyl derivatives of 2-amino-l-phenylpropan-l-ol w~e carried out employing the Pictet-Cams modification ofthe BischlerNapieralski reaction. The formation of4, 5-dihydro-oxazoles orisoquinolines depends on the substituents
Md. Sharif, Atan, O. Fitton, Alan
core
Excimer Formation in Aqueous Solutions of Hosts and Application in Synthesis
This review explores how host‐mediated excimer formation in water, facilitated by supramolecular confinement enhances photochemical synthesis. By improving solubility, local concentrations, and orientational control, these systems can boost efficiency and selectivity in reactions like photocycloadditions and photodimerizations.
Doğan Akbulut +3 more
wiley +1 more source
Bacteriocins are peptide-derived molecules produced by bacteria, whose recently-discovered functions include virulence factors and signalling molecules as well as their better known roles as antibiotics.
Freed, Stefan D +3 more
core +1 more source
Regioselective Formation of 2,5-Disubstituted Oxazoles Via Copper(I)-Catalyzed Cycloaddition of Acyl Azides and 1-Alkynes [PDF]
The reaction of 1-alkynes with acylazides in the presence of [Tpm*,BrCu(NCMe)]BF4 (Tpm*,Br = tris(3,5-dimethyl-4-bromopyrazolyl)methane) as the catalyst provides 2,5-oxazoles in moderate to high yields.
Cano Rico, Israel +3 more
core +1 more source
2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone serves as a versatile oxidant and redox catalyst for CC bond formation through hydride abstraction or single‐electron transfer. Stoichiometric and catalytic systems enable benzylic, allylic, and aromatic CH activation under mild, metal‐free conditions, providing sustainable routes to complex and bioactive ...
Dohoon Cha, Sun‐Joon Min
wiley +1 more source
Synthesis and antitumor activity of mechercharmycin A analogues [PDF]
Several analogs of the cytotoxic thiopeptide IB-01211 or Mechercharmycin A (1) have been synthetized. The cytotoxicity of 1 and the synthetized analogs was evaluated against a panel of three human tumor cell lines.
Albericio Palomera, Fernando +5 more
core +2 more sources
Insights into the Electronic Structure of CuII Bound to an Imidazole Analogue of Westiellamide. [PDF]
Three synthetic analogues of westiallamide, HL, have previously been synthesized (HL) that have a common backbone (derived from l-valine) with HL but differ in their heterocyclic rings (imidazole, oxazole, thiazole, and oxazoline).
Comba, Peter +6 more
core +1 more source
Thiopeptide Antibiotics: Retrospective and Recent Advances
Thiopeptides, or thiazolyl peptides, are a relatively new family of antibiotics that already counts with more than one hundred different entities.
Xavier Just-Baringo +2 more
doaj +1 more source

