Results 41 to 50 of about 5,322 (210)

Diradicalar Character and Ring Stability of Mesoionic Heterocyclic Oxazoles and Thiazoles by Ab Initio Mono and Multi-Reference Methods

open access: yesMolecules, 2020
Mesoionics are neutral compounds that cannot be represented by a fully covalent or purely ionic structure. Among the possible mesomeric structures of these compounds are the diradical electronic configurations.
Antonio João da Silva Filho   +2 more
doaj   +1 more source

Recurrence of the oxazole motif in tubulin colchicine site inhibitors with anti-tumor activity

open access: yesEuropean Journal of Medicinal Chemistry Reports, 2021
Because of its wide spectrum of targets and biological activities, the oxazole ring is a valuable heterocyclic scaffold in the design of new therapeutic agents with anticancer, antiviral, antibacterial, anti-inflammatory, neuroprotective, antidiabetic ...
Marilia Barreca   +7 more
doaj   +1 more source

C‐Terminal Functionalization Methods of Amino Acids, Peptides, and Proteins

open access: yesChemistry – A European Journal, EarlyView.
C‐terminal functionalization offers powerful routes to peptide and protein diversification, yet epimerization, hydrolysis, and selectivity remain key challenges. This Review surveys enzymatic, decarboxylative, and condensation strategies, highlighting advances toward chemo‐ and regioselective, protecting‐group‐free, atom‐efficient methods applicable to
Jay Hanssens   +3 more
wiley   +1 more source

Componentes voláteis do café torrado. Parte I: compostos heterocíclicos Volatile components in roasted coffee. Part I: heterocyclic compounds

open access: yesQuímica Nova, 1999
A review of heterocyclic compounds in roasted coffee is presented. The contents, precursors and sensorial properties of furans, pyrroles, oxazoles, thiazoles, thiophenes, pyrazines and pyridines are discussed.
Carlos Alberto Bastos De Maria   +2 more
doaj   +1 more source

In Silico and In Vitro Assessment of Antimicrobial and Antibiofilm Activity of Some 1,3-Oxazole-Based Compounds and Their Isosteric Analogues

open access: yesApplied Sciences, 2022
In this paper, we report on the antimicrobial activity assessment of 49 compounds previously synthesized as derivatives of alanine or phenylalanine that incorporate a 4-(4-X-phenylsulfonyl)phenyl fragment (X = H, Cl, or Br), namely 21 acyclic compounds ...
Theodora-Venera Apostol   +8 more
doaj   +1 more source

Heteroaryl‐Iminoalkoxide Complexes of Tin(II): Structure‐Property Relationships Governing Volatility and Thermal Stability

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
A family of heteroaryl‐iminoalkoxide Sn(II) complexes has been synthesized to investigate structure‐property relationships relevant to atomic layer deposition and metal‐organic vapor deposition. Systematic modification of the ligand architecture reveals a strong influence on volatility and thermal stability for the parent metal complexes.
Oliver W. S. Clark, Andrew L. Johnson
wiley   +1 more source

Recent advances and prospects for high‐efficiency blue hot exciton organic light‐emitting diodes

open access: yesFlexMat, EarlyView.
Blue organic light‐emitting diodes (OLEDs) face great challenges in achieving the balance between color purity, device efficiency, and stability. Hot exciton materials offer a solution by rapidly converting non‐emissive triplet excitons into singlet ones through a high‐lying reverse intersystem crossing process.
Xiaoen Shi   +3 more
wiley   +1 more source

Synthesis of 5-(7 '-indolyl)oxazoles and 2,5-di-(7 '-indolyl)oxazoles

open access: yes, 2013
The synthesis of 7-aminoacetylindoles was achieved via the hydrogenation of 7-acylcyanides, which were produced through the oxidation of indole-7-cyanohydrin silylether intermediates.
Kumar, Naresh   +3 more
core   +1 more source

A Convenient Oxazole C-2 Protecting Group:  The Synthesis of 4- and 5-Substituted Oxazoles via Metalation of 2-Triisopropylsilyloxazoles

open access: yes, 2016
Metalation of oxazoles at the 4 and 5 position was achieved after regioselective C-2 silyl protection. Removal of the protecting group was then accomplished under mild conditions allowing for a straightforward preparation of C-5 monosubstituted and C-4,5
Benjamin Marcune (1508755)   +2 more
core   +2 more sources

Dietary impact of agri‐food by‐products on the volatile composition of Tenebrio molitor larvae

open access: yesJournal of the Science of Food and Agriculture, EarlyView.
Abstract BACKGROUND Incorporating Tenebrio molitor larvae as ingredients in common foods is a promising strategy to encourage their consumption. To achieve this, knowing their volatile profile and the factors that may modify the profile is essential. The effect of larval feeding over volatile composition remains under‐researched, for this reason; the ...
María Lourdes Morales   +5 more
wiley   +1 more source

Home - About - Disclaimer - Privacy