Results 71 to 80 of about 5,187 (206)

Fish Sperm Subpopulations Detection, Separation, and Application: Current State and Trends

open access: yesReviews in Aquaculture, Volume 18, Issue 4, September 2026.
Modern advances in sperm biology highlight the necessity of recognising intra‐ejaculate heterogeneity as a central concept for advancing both the fundamental understanding of fertilisation processes and the development of artificial reproduction techniques in fishes. ABSTRACT Sperm subpopulations represent a fundamental manifestation of intra‐ejaculate
Viktoriya Dzyuba   +2 more
wiley   +1 more source

Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 32, 24 August 2026.
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley   +1 more source

Lewis‐Acidic Properties and Catalytic Behavior of Hydroboration‐ and Diolysis‐Derived NHC‐Stabilized Borenium Cations

open access: yesChemistry – A European Journal, Volume 32, Issue 31, 18 August 2026.
A series of thirteen (N‐heterocyclic carbene) NHC‐stabilized borenium cations is synthesized from NHC→BH3 complexes via hydroboration and condensation with diols. The novel compounds are fully characterized. Eight crystal structures are presented. Kinetic and NMR data show how the structural features translate to catalytic activity in hydrosilylation ...
Michał Jakubczyk   +4 more
wiley   +1 more source

Oxazoles as dienophiles in Diels-Alder reactions

open access: yes, 1986
2-(N-benzyl-N-methylamino)-oxazoles undergo (4+2)-cycloadditions across the C4-C5 bond by electron deficient ...
Paola Pedrini   +13 more
core   +1 more source

Gallium-containing polymer brush film as efficient supported Lewis acid catalyst in a glass microreactor

open access: yesBeilstein Journal of Organic Chemistry, 2013
Polystyrene sulfonate polymer brushes, grown on the interior of the microchannels in a microreactor, have been used for the anchoring of gallium as a Lewis acid catalyst.
Rajesh Munirathinam   +7 more
doaj   +1 more source

Synthesis of Highly Substituted Oxazoles through Iodine(III)-Mediated Reactions of Ketones with Nitriles

open access: yesMolecules, 2012
In the presence of trifluoromethanesulfonic acid (TfOH) or bis(trifluoromethane-sulfonyl)imide (Tf2NH), iodosobenzene (PhI=O) efficiently promoted the reactions of dicarbonyl compounds as well as monocarbonyl compounds with nitriles to give 2,4 ...
Yuji Hanzawa, Akio Saito, Nao Hyodo
doaj   +1 more source

Triflic anhydride-mediated synthesis of oxazoles

open access: yes, 2009
N-Acyl amino acid esters undergo triflic anhydride-mediated cyclodehydration to form oxazoles and bisoxazoles in a simple one-pot transformation. © 2008 Elsevier Ltd.
Mecinovic, J   +3 more
core   +1 more source

MW-Assisted Synthesis of Eight New 6-Nitrilmethyl Pyrrolo[3,4-b]pyridin-5-Ones via a Domino Process: aza Diels–Alder/N-Acylation/Aromatization

open access: yesProceedings, 2019
An efficient Microwave (MW)-assisted synthesis of eight new 6-nitrilmethyl-pyrrolo[3,4-b]pyridin-5-ones via a domino process: aza Diels–Alder/N-acylation/aromatization (dehydration–decarboxylation) from their corresponding 2-aminonitrile ...
Manuel A. Rentería-Gómez   +4 more
doaj   +1 more source

General Methodology for the Preparation of 2,5-Disubstituted-1,3-oxazoles

open access: yes, 2016
Deprotonation of 2-(phenylsulfonyl)-1,3-oxazole (1) readily provides a useful C-5 carbanion that is reactive with a variety of electrophiles. Aldehydes and ketones are useful substrates, and the formation of 5-iodo- and 5-tri-n-butylstannyl oxazoles ...
Liangfeng Fu (1863826)   +1 more
core   +1 more source

Stereoselective Direct Copper-Catalyzed Alkenylation of Oxazoles with Bromoalkenes

open access: yes, 2016
A copper-catalyzed direct alkenylation of oxazoles with bromoalkenes has been developed. The method is both regio- and stereoselective and tolerates a variety of functional groups.
Sandrine Piguel (2145475)   +3 more
core   +1 more source

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