Results 81 to 90 of about 5,322 (210)

Triflic anhydride-mediated synthesis of oxazoles

open access: yes, 2016
N-Acyl amino acid esters undergo triflic anhydride-mediated cyclodehydration to form oxazoles and bisoxazoles in a simple one-pot transformation. © 2008 Elsevier Ltd.

core   +1 more source

MW-Assisted Synthesis of Eight New 6-Nitrilmethyl Pyrrolo[3,4-b]pyridin-5-Ones via a Domino Process: aza Diels–Alder/N-Acylation/Aromatization

open access: yesProceedings, 2019
An efficient Microwave (MW)-assisted synthesis of eight new 6-nitrilmethyl-pyrrolo[3,4-b]pyridin-5-ones via a domino process: aza Diels–Alder/N-acylation/aromatization (dehydration–decarboxylation) from their corresponding 2-aminonitrile ...
Manuel A. Rentería-Gómez   +4 more
doaj   +1 more source

Active γ-manganese dioxide promoted conversion of 4,5-dihydro-1,2-oxazoles to 1,2-oxazoles.

open access: yes, 1977
Dehydrogenation of seven dihydrooxazoles I (R1 = Ph, octyl, Me, Ph, 2-​naphthyl, CO2Me, hexyl; R2 = H, NO2; R3 = Me, Ph, (CH2)​2CO2Me) with γ-​MnO2 gave 97-​100​% oxazoles ...
BENETTI, Simonetta   +3 more
core   +1 more source

Synthesis of 2‑(Hetero)aryl-5-(trimethyl­silyl­ethynyl)­oxazoles from (Hetero)aryl­acrylic Acids

open access: yes, 2015
A three-step method for the synthesis of 2-(hetero)­aryl-5-(trimethylsilyl­ethynyl)­oxazoles is described. Easily accessible bis­(trimethylsilyl)­acetylene and acrylic acid derivatives are used as starting materials for the preparation of mono- and ...
Alena S. Pankova (1617217)   +2 more
core   +1 more source

Solid-Phase Rhodium Carbenoid Reactions:  An N−H Insertion Route to a Diverse Series of Oxazoles

open access: yes, 2016
The solid-phase synthesis of a series of oxazoles is described. The key step in the construction of these molecules involves the rhodium-catalyzed decomposition of polymer-bound α-diazo-β-ketoesters.
Carsten Spanka (2153536)   +2 more
core   +1 more source

From Propargylic Amides to Functionalized Oxazoles: Domino Gold Catalysis/Oxidation by Dioxygen

open access: yes, 2016
A new, highly efficient, and atom-economic access to a series of functionalized 2,5-disubstituted oxazoles from propargylic amides is reported. A series of propargylic amides were transformed to the corresponding alkylideneoxazolines by a gold­(I ...
A. Stephen K. Hashmi (1264071)   +3 more
core   +2 more sources

Aromaticities of Five Membered Heterocycles through Dimethyldihydropyrenes Probe by Magnetic and Geometric Criteria

open access: yesJournal of Chemistry, 2015
Aromaticities of five membered heterocycles, containing up to three heteroatoms, are quantified through the dimethyldihydropyrene (DHP) probe. Bond fixation caused by the fusion of heterocycles to the dimethyldihydropyrene nucleus (DHPN) was measured by ...
Maria, Khurshid Ayub
doaj   +1 more source

On the addition of lithiated 2-alkyl- and 2-(chloroalkyl)-4,5-dihydro-1,3-oxazoles to nitrones - A mechanistic investigation

open access: yes, 2002
The addition of 2-(lithioalkyl)-4,5-dihydro-1,3-oxazoles 2a-c and 2-[chloro(lithio)alkyl]-4,5-dihydro-1,3-oxazoles 2d,e to nitrones 3 has been studied.
SAVERIO FLORIO   +3 more
core   +1 more source

Iodine-mediated new strategy for the synthesis of 2,5-disubstituted oxazoles from methyl ketones and TosMIC

open access: yes, 2018
A new strategy has been developed for the construction of oxazoles from methyl ketones and TosMIC via self-sorting oxidative domino reaction strategy. In contrast to its usual reactivity as C–N≡C synthon in the synthesis of oxazoles, TosMIC was utilized ...
Palakodety Radha Krishna (2130520)   +2 more
core   +1 more source

Stereoselective Direct Copper-Catalyzed Alkenylation of Oxazoles with Bromoalkenes

open access: yes, 2016
A copper-catalyzed direct alkenylation of oxazoles with bromoalkenes has been developed. The method is both regio- and stereoselective and tolerates a variety of functional groups.
Sandrine Piguel (2145475)   +3 more
core   +1 more source

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