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Proanthocyanidins in cereals and pseudocereals
Critical Reviews in Food Science and Nutrition, 2018Proanthocyanidins (PAs) are a class of oligomeric flavonoids found in a variety of plant foods. Intake of PAs in human diet has been associated with a reduced occurrence of various chronic disorders. Cereal and pseudocereal grains are staple food items.
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Flavanols and Proanthocyanidins
2014There are many kinds of natural, oligo- and polymeric materials with very specific, almost unique properties. In the field of redox active secondary metabolites, the class of ‘condensed’ polyphenolic flavonoids, often referred to as proanthocyanidins or––at higher molecular weight––as tannins clearly stands out. Such substances are found in many edible
Hadi Ebrahimnejad +2 more
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Chromatography of Proanthocyanidins
1989Current trends in chromatographic isolation and analyses of proanthocyanidins are reviewed. Preparative isolations by low pressure column chromatography can be carried out using a variety of gel types. Often, repeated separations are required to obtain pure compounds, and it has been found advantageous to alternate each separation with a different gel ...
Joseph J. Karchesy +4 more
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Proanthocyanidins in the Apple
Journal of Food Science, 1966SUMMARY A study was conducted on the acetone‐ and ethyl‐acetate‐extractable flavan polyphenols of Waldhöfler apples, an astringent‐tasting juice variety. The extracts were examined by cellulose thin‐layer chromatography with 5% n‐butanol and n‐butanol—acetic acid—water (BAW) as the developing solvents ...
J. P. VAN BUREN, G. SENN, H. NEUKOM
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Biosynthesis of proanthocyanidins
Journal of the Chemical Society, Chemical Communications, 1975The incorporation of 4′,5,7-trihydroxydihydroflavonol into the dimeric procyanidin B-4 in Rubus idaeus indicates that both flavan-3,4-diols and flavan-3-ols are derived biogenetically from dihydroflavonols.
Edmon Wong, Edward J. Birch
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Conformations of Proanthocyanidins
1992The application of high resolution 1H-NMR and empirical (MM2, MMX) as well as semiempirical (MNDO, AMI, PM3) theoretical methods in the conformational analysis of proanthocyanidins have been the subject of much study. The E:A (B-ring equatorial or axial) ratios calculated for 4-arylflavan-3-ol model compounds, carefully selected to incorporate all ...
Jan P. Steynberg +4 more
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Plant proanthocyanidins. Part II. Proanthocyanidin-A2 and its derivatives
Journal of the Chemical Society, Perkin Transactions 1, 1974The 2,7″-epoxy-4,8″-biflavan structure (1) has been deduced for the natural proanthocyanidin-A2 on the basis of spectroscopic (13C and 1H n.m.r.) and chemical evidence. Spectroscopic data are also outlined which lead, in association with biogenetic arguments, to a proposal (1a) for the absolute stereochemistry of the natural product.
David Jacques +3 more
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Proanthocyanidins ofPolygonum coriarium. IV. Structures of proanthocyanidins T3 and T4
Chemistry of Natural Compounds, 1997Two oligomeric proanthocyanidins have been isolated from the roots ofPolygonum coriarium. By a study of their physical properties and spectral characteristics and analysis of the results of chemical transformations, the chemical structures of these compounds have been established as: (−)-epicatechin-77[O-β-D-glucopyranosyl]3\(\xleftarrow{6}\) O-²-D ...
B. M. Keneshov +4 more
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Proanthocyanidins ofPolygonum coriarium III. Structures of proanthocyanidins T1 and T2
Chemistry of Natural Compounds, 1997The roots ofPolygonum coriarum have yielded two oligomeric proanthocyanidins, T1 and T2, and their structures have been established: 3-O-galloyl-7-O-[O-(6-O-galloyl)-β-D-glucopyranosyl]-(−)-epigallocatechin-(4β-8)-(−)-epicatechin-(4β-8)-(−)-epicatechin-(4β-8)-(−)-epigallocatechin 3-O-gallate (T1) and (−)-epicatechin-(4β-8)-[3-O-galloyl ...
B. M. Keneshov +5 more
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Variation of Proanthocyanidins in Lotus Species
Journal of Chemical Ecology, 2006The proanthocyanidin (PA) chemistry of 12 Lotus species of previously unknown PA content was examined in comparison with agricultural cultivars of L. pedunculatus, L. corniculatus, and L. tenuis and a "creeping" selection of L. corniculatus. Herbage harvested in winter 2000 and again in spring had extractable PA concentrations, estimations of which ...
Subathira, Sivakumaran +6 more
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