Results 11 to 20 of about 27,892 (233)
Rapid and Scalable Halosulfonylation of Strain‐Release Reagents**
Angewandte Chemie, Volume 135, Issue 3, January 16, 2023., 2023 A one‐pot halosulfonylation of strained hydrocarbons is described that proceeds under practical, scalable and mild conditions. Sulfonyl halides featuring aryl, heteroaryl and alkyl substituents are generated in situ from sulfinate salts and convenient halogen atom sources. This chemistry enables the synthesis of an array of halogen/sulfonyl‐substituted
Helena D. Pickford +7 more
wiley +2 more sources
Angewandte Chemie, Volume 134, Issue 51, December 19, 2022., 2022 The single component flavin reductase/flavin dependent halogenase AetF catalyzes halogenation of a diverse set of substrates. High site selectivity, activity on relatively unactivated substrates, and high enantioselectivity for atroposelective bromination and bromolactonization was demonstrated.
Yuhua Jiang +10 more
wiley +2 more sources
SUBSTITUTED 4-NITROSOPYRAZOLES IN THE DIELS-ALDER REACTION
Siberian Journal of Life Sciences and Agriculture, 2021 Background. 4-Nitrosopyrazoles have become widespread in the pharmaceutical industry and in chemistry due to their high reactivity and biological activity. However, the interaction of 3,5-substituted 4-nitroso-1H-pyrazoles with diene hydrocarbons has not
Darya S. Volkova +4 more
doaj +1 more source
Nickel-Catalyzed, One-Pot Synthesis of Pyrazoles
Chemistry Proceedings, 2022 Recently, multi-component, one-pot reactions have been shown to be efficient and environmentally friendly methods compared to traditional, linear-step syntheses.
Nassima Medjahed +4 more
doaj +1 more source
Synthesis of Dihydropyrano[3,2-c]pyrazoles via Double Bond Migration and Ring-Closing Metathesis
Molecules, 2019 Three types of pyrazole-fused heterobicycles, i.e., 1,5-, 1,7-, and 2,5-dihydropyrano[3,2-c]pyrazoles, were synthesized from 4-allyloxy-1H-pyrazoles. A sequence of the Claisen rearrangement of 4-allyloxy-1H-pyrazoles, ruthenium-hydride-catalyzed double ...
Yoshihide Usami +5 more
doaj +1 more source
Journal of Saudi Chemical Society, 2015 Several-1-carbothioamide-3,5-dimethyl-4-[(substituted phenyl) diazenyl] pyrazoles 2a–d, 1-(pyridine-4-ylcarbonyl)-3,5-dimethyl-4-[(substituted phenyl) diazenyl] pyrazoles 3a–d, 1-(5-chloro-6-fluoro-1,3-benzothiazole-2-yl)thiocarbamoyl-3,5-dimethyl-4 ...
Sabir Hussain, Deepika Kaushik
doaj +1 more source
Preparation of novel acyl pyrazoles and triazoles by means of oxidative functionalization reactions
Heterocyclic Communications, 2023 Novel acyl pyrazoles and acyl triazoles have been prepared by means of the oxidative amidation of aldehydes in the presence of the requisite azole. Yields range from modest to good in both cases, and some limitations of the substrate scope have been ...
Wadey Geoffrey P. +3 more
doaj +1 more source
Magnetocaloric effect in {[Fe(pyrazole)$_4$]$_2$[Nb(CN)$_8$]$\cdot$4H$_2$O}$_n$ molecular magnet [PDF]
JMMM 354 (2014) 359, 2013 Magnetocaloric effect in {[Fe(pyrazole)$_4$]$_2$[Nb(CN)$_8$]$\cdot$4H$_2$O}$_n$ molecular magnet is reported. It crystallizes in tetragonal I4$_1$/a space group. The compound exhibits a phase transition to a long range magnetically ordered state at $T_\mathrm{c}\approx$8.3 K.
arxiv +1 more source
Bulletin of the Chemical Society of Ethiopia, 2014 Some aryl-aryl 1H pyrazoles have been synthesised by cyclization of aryl chalcones and hydrazine hydrate in the presence of SOCl2. The yields of the pyrazoles are more than 85%.
K. Ranganathan +5 more
doaj +1 more source
Molecules, 2018 Synthesis of novel pyrazole-fused heterocycles, i.e., dihydro-1H- or 2H-oxepino[3,2-c]pyrazoles (6 or 7) from 4-allyloxy-1H-pyrazoles (1) via combination of Claisen rearrangement and ring-closing metathesis (RCM) has been achieved.
Yoshihide Usami +3 more
doaj +1 more source