Results 31 to 40 of about 38,574 (278)

Computational Modeling of Reticular Materials: The Past, the Present, and the Future

open access: yesAdvanced Materials, EarlyView.
Reticular materials are advanced materials with applications in emerging technologies. A thorough understanding of material properties at operating conditions is critical to accelerate the deployment at an industrial scale. Herein, the status of computational modeling of reticular materials is reviewed, supplemented with topical examples highlighting ...
Wim Temmerman   +3 more
wiley   +1 more source

Hydrazones as Singular Reagents in Asymmetric Organocatalysis [PDF]

open access: yes, 2016
This Minireview summarizes strategies and developments regarding the use of hydrazones as reagents in asymmetric organocatalysis, their distinct roles in nucleophile–electrophile, cycloaddition, and cyclization reactions.
Fernández Fernández, Rosario Fátima   +4 more
core   +1 more source

PYRAZOLE DERIVATIVES.

open access: yes, 1939
An indolylpyrazolone derivative has been synthesised The syntheses of some pyrrolapyrazole and dipyrazole derivatives have been described.
TEJENDRA NATH GHOSH, DEBABRATA DAS-GUPTA
openaire   +2 more sources

Hierarchically MOF‐Based Porous Monolith Composites for Atmospheric Water Harvesting

open access: yesAdvanced Materials, EarlyView.
This review explores the design of hierarchical porous materials for atmospheric water harvesting, focusing on metal‐organic frameworks (MOFs) and porous monoliths. Emphasis is placed on integrating MOF nanoscale porosity with the microscale channels of monolithic scaffolds to enhance sorption‐desorption performance.
Mahyar Panahi‐Sarmad   +7 more
wiley   +1 more source

Supramolecular Chemistry in Metal–Organic Framework Materials

open access: yesAdvanced Materials, EarlyView.
This review highlights synergies between reticular chemistry and supramolecular chemistry. The role of supramolecular interactions in determining framework…guest interactions and attempts to understand dynamic behavior in metal–organic frameworks (MOFs), particularly emphasizing the development of crystal sponges, studying reactions in frameworks and ...
Eugenia Miguel‐Casañ   +3 more
wiley   +1 more source

Advancements in Understanding the Physicochemical Properties of Reticular Materials: An In Situ and Operando Spectroscopic Perspective

open access: yesAdvanced Materials, EarlyView.
This review explores how in situ and operando spectroscopic techniques reveal the real‐time behavior of reticular materials, including MOFs and COFs. These methods track material formation and functionalization, structural changes, defect formation, dynamic responses to external triggers, and catalytic processes.
Bettina Baumgartner   +4 more
wiley   +1 more source

Rhodium‐Catalyzed Oxidative CH o‐Arylation of s‐Aryltetrazines with Aryl Boronic Acids: One‐Step Selective Access to T‐Shaped and Z‐Shaped Polyaromatics

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A one‐step regioselective access to T‐Shaped and Z‐Shaped polyaromatics s‐tetrazines by a rhodium‐catalyzed oxidative CH o‐functionalization is reported. Electron‐rich aryl coupling partners display a higher reactivity than electron‐poor aryl, and allow the formation of poly(hetero)aromatic derivatives while avoiding 1,4‐azaphilic addition of the ...
Oumaima Abidi   +6 more
wiley   +1 more source

Metal Acetylides in Cycloaddition Reactions [PDF]

open access: yes, 2017
This review highlights recent advances in the synthesis of (hetero)aromatic systems via cycloaddition reactions of alkynylmetals with dienes and dipoles.
Comas-Barceló, J., Harrity, J.P.A.
core   +1 more source

Azabicyclo[1.1.0]butyl‐Substituted Sulfonimidoyl Fluoride: Electrophilic Hub Bridging Late‐Stage Azetidine Incorporation with Sufex Chemistry

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
GA: Strained small motifs and SuFEx hubs are of increasing importance in drug discovery to enable efficient late‐stage functionalization. Here, the synthesis of bench‐stable azabicyclo[1.1.0]butyl‐substituted sulfonimidoyl fluoride as an electrophilic hub with dual activation mode is reported.
Defne Serbetci   +5 more
wiley   +1 more source

Cu-catalysed pyrazole synthesis in continuous flow [PDF]

open access: yes, 2016
The synthesis of 1,4-disubstituted pyrazoles via the cycloaddition reaction of sydnones and terminal alkynes has been achieved employing silica-supported copper catalysts. Furthermore, this methodology has been successfully implemented in continuous flow
Arbaciauskiené   +26 more
core   +3 more sources

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