Results 101 to 110 of about 70,546 (390)
The title compound, C31H26N4O2S, crystallizes in a triclinic centrosymmetric lattice with two molecules in the unit cell. The five-membered thiazole and pyrrolidine rings adopt twisted and envelope conformations, respectively.
C. Muthuselvi+6 more
doaj +1 more source
The title compound, C23H24N2O9, is a tetra-substituted pyrrolidine derivative with a twisted conformation, with the twist evident in the C—C bond bearing the adjacent acetyloxy substituents.
Sofia Dallasta Pedroso+8 more
doaj +1 more source
Halogenation Thermodynamics of Pyrrolidinium-Based Ionic Liquids [PDF]
Room-temperature ionic liquids (RTILs) exhibit large difference between melting and boiling points. They are highly tunable thanks to numerous accessible combinations of the cation and the anion. On top of that, cations can be functionalized using methods of organic chemistry.
arxiv
Opposite effects of two zinc(II) dithiocarbamates on NF-kB pathway [PDF]
Inhibiting nuclear factor-kappaB (NF-kB) activation in anticancer and antiinflammatory therapy is of topical interest. Current research in molecular biology has dramatically advanced in the understanding of the cellular events involved in NF-kB induction.
Boris Cvek+5 more
core +2 more sources
Radical‐Polar Crossover Bicyclization Enables a Modular Synthesis of Saturated Bicyclic Amines
Herein, we report the successful realization of a radical‐polar crossover bicyclization reaction from easily available cyclopropylamines and substituted alkenes through photoredox catalysis. This approach introduces an innovative methodology for the de novo synthesis of a diverse collection of 4/5‐, 5/5‐, 6/5‐,7/5‐ and 5/6‐fused saturated bicyclic ...
Dewei Feng+4 more
wiley +1 more source
Concise total syntheses of five leuconoxine alkaloids have been achieved using a pyrrole‐centered strategy, which features a newly developed palladium/norbornene‐catalyzed pyrrole double C─H functionalization method, a divergent late‐stage oxidative dearomatization tactic, and no use of protecting groups.
Xin Liu+5 more
wiley +2 more sources
The gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation reaction offers a simple and efficient method for the synthesis of pyrrolidine derivatives in moderate to excellent product yields and with ...
Ya-Ping Xiao, Xin-Yuan Liu, Chi-Ming Che
doaj +1 more source
Green synthesis of highly functionalized octahydropyrrolo[3,4-c]pyrrole derivatives using subcritical water, and their anti(myco)bacterial and antifungal activity [PDF]
A series of novel 2-(thiazol-2-yl)-octahydropyrrolo[3,4-c]pyrroles was synthesized by reaction of octahydropyrrolo[3,4-c]pyrrole N-benzoylthiourea derivatives and α-haloketones in subcritical water at 130 °C in 75-91% yield.
De Coen, Laurens+4 more
core +1 more source
Rigorous Conformational Analysis of Pyrrolidine Enamines with Relevance to Organocatalysis
It has been suggested that the origin of regio- and stereoselectivity in Michael addi- tions of pyrrolidine enamines is achieved by thermodynamic rather than kinetic control through distinct conformational preferences of the enamines.
Tamara Husch+3 more
semanticscholar +1 more source
A simple and effective non‐solvent‐induced microstructure rearrangement (MSR) technique is proposed to enhance the gas separation performance of Pebax 2533 membranes. By immersing Pebax 2533 membranes in amino acid salt solutions to induce MSR, the CO2 permeability of the Pebax 2533‐GlyK 10 wt.% membrane reached 1180 Barrer.
Jing Wei+16 more
wiley +1 more source