Results 121 to 130 of about 36,836 (288)
Studies toward New Anti-Cancer Strategies Based on ?-Mannosidase Inhibition
Changes in the glycosylation pattern of cellular glycoproteins constitute a hallmark in human cancer and influence tumor progression, suggesting that inhibitors of selected glycosidases may control cancer progression.
Sandrine Gerber-Lemaire +1 more
doaj +1 more source
High‐Voltage Cathode Materials for Sodium‐Ion Batteries: Advances and Challenges
This review explores the role of high‐voltage cathode materials in enhancing the performance of SIBs. It focuses on strategies to improve energy density, rate capacity, and stability, addressing challenges like phase transitions, metal migration, and electrolyte degradation.
Congqi Ren, Yulian Dong, Yong Lei
wiley +1 more source
In this work, we study the electronic interactions of MoS2 and WS2 covalently interfaced with boron dipyrromethene derivatives across different regions of the light spectrum. Under light irradiation, energy and electron transfer processes are observed, revealing environment‐invariant modifications of the BODIPY core induced by different functional ...
Ruben Canton‐Vitoria +5 more
wiley +1 more source
Enantiodivergent α-Amino C–H Fluoroalkylation Catalyzed by Engineered Cytochrome P450s [PDF]
The introduction of fluoroalkyl groups into organic compounds can significantly alter pharmacological characteristics. One enabling but underexplored approach for the installation of fluoroalkyl groups is selective C(sp^3)–H functionalization due to the ...
Arnold, Frances H. +3 more
core
A steric tethering approach enables palladium-catalysed C-H activation of primary amino alcohols. [PDF]
Aliphatic primary amines are a class of chemical feedstock essential to the synthesis of higher-order nitrogen-containing molecules, commonly found in biologically active compounds and pharmaceutical agents.
A McNally +52 more
core +3 more sources
Ximenia americana L. From Popular Use to Anti‐Inflammatory Activities: A Comprehensive Review
ABSTRACT Ximenia americana (L.), known as “yellow plum,” “sea lemon,” or “Brazilian plum,” is a tropical/subtropical plant widely used in traditional medicine. Its roots, leaves, flowers, stem, and fruits are traditionally employed to treat various inflammatory disorders.
Bruno Anderson F. Silva +9 more
wiley +1 more source
Results of GC–MS Analyses of 40 Extracts of Diabetes Devices
Forty acetone extracts of 27 diabetes devices were investigated by gas chromatography–mass spectrometry. Two hundred eighty four individual chemicals were identified. All 40 extracts contained one or more chemicals that were previously identified as allergens in diabetes devices causing allergic Contact Dermatitis.
Emma M. van Oers +4 more
wiley +1 more source
Photocatalyzed Ring Expansion of α‐Ketosulfonylaziridines: Ready Access to δ‐Sultams
A novel radical–polar crossover (RPC) photoredox‐catalyzed reaction for the synthesis of δ‐sultams from N‐sulfonyl α‐ketoaziridines through a controlled ring opening–expansion process is presented. This method allows the easy access to sultams with an unprecedented substitution pattern in up to 85% yield and 2:1 d.r., and highlights the potential of ...
Marco M. Mastandrea +7 more
wiley +2 more sources
Simple access to alkylated 3D scaffold via oxidative radical decarboxylation, trapping of iminium, and successive reaction with organometallic reagent in the presence of BF3 . ABSTRACT Cyclic amines are vital scaffolds in bioactive molecules and drug discovery, often functionalized via electrochemical Shono‐type oxidation to access N‐acyliminium ...
Dario Corbisiero +7 more
wiley +1 more source
A bench‐stable boryl thianthrenium dication is synthesized via thianthrenation of vinyl MIDA boronate. This novel dication enables metal‐free, chemo‐, and diastereoselective late‐stage aziridination with diverse nitrogen nucleophiles. The strategic significance is further showcased by one‐pot electrochemical and asymmetric protocols and versatile ...
Veerabhadra R. Vulupala +7 more
wiley +2 more sources

