A Multicatalytic Cascade for the Stereoselective Synthesis of 1,4-Chiral Nitro Alcohols. [PDF]
Ascaso-Alegre C +4 more
europepmc +1 more source
Selective isomerization of 2,3-disubstituted butanediacetal esters and thioesters using lithium and sodium enolates: effects of bases and additives on stereoselectivity. [PDF]
Drop A +2 more
europepmc +1 more source
Selective and Tunable Routes for Glucose to Fructose Conversion Using MgCl<sub>2</sub> Catalysis and Comparison to Other Metal Ions. [PDF]
Maragani R, Meier S.
europepmc +1 more source
Catalytic asymmetric functionalization of bicyclo[1.1.0]butane boronic esters enabled by 1,2-oxygen migration. [PDF]
Zhu XY, Ji CL, Dong TG, Gao DW.
europepmc +1 more source
Stereodivergent access to α- and β-azanucleosides <i>via</i> catalyst-free, achiral modulator-controlled iodocyclization: a concise synthesis of forodesine. [PDF]
Zhong Y +9 more
europepmc +1 more source
Catalytic Amyloids: Turning Fibrils Into Biocatalysts
Amyloids, traditionally associated with diseases, have emerged as versatile catalytic scaffolds. From natural amyloid sequences to bioinspired and de novo designs, we highlight strategies to construct catalytic active sites and anchor enzymes onto fibrils, creating versatile nanomaterials with tunable activities. ABSTRACT Amyloids have been regarded as
Alessandra Esposito +3 more
wiley +1 more source
Difluorinative Cyclopropene Rearrangement by I(I)/I(III) Catalysis: Regio- and Stereoselective Synthesis of Allyl Difluorides. [PDF]
Wang ZX +3 more
europepmc +1 more source
Synthetic Studies Towards Darobactin A
The urgent need for new antibiotics led us to develop a new methodology for the synthesis of the natural product darobactin A selectively targeting gram‐negative bacteria. This study provides new insights into the synthesis of strained indole‐containing macrocycles.
Till Steiner +4 more
wiley +1 more source
Catalyst-controlled stereodivergent synthesis of polysubstituted alkenes. [PDF]
Huang C +7 more
europepmc +1 more source
Bis‐Furans: A Sustainable Source of Diverse Molecular Architectures
A concise synthetic route to diverse acyclic and heterocyclic compounds has been developed by combining hetero‐Diels–Alder reactions, DBU‐promoted ring openings, and Lewis base‐catalyzed annulations. Nitrosoalkenes reacted with furan derivatives to form 4a,7a‐dihydro‐4H‐furo[2,3‐e][1,2]oxazines, which underwent DBU‐promoted rearrangements to 6H‐1,2 ...
Ana L. Cardoso +2 more
wiley +1 more source

