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Hidden Activities of Tyrosine Phenol-Lyase and Tryptophan Indole-Lyase: Recombinant PLP-Dependent C–C Lyases as New Biocatalysts for Antimicrobial Thiosulfinate Generation [PDF]
PharmaceuticalsBackground: Lyases are used in a wide scope of applications, making them invaluable tools in both industrial biotechnology and molecular biology. Many examples of lyases belong to the extensive family of pyridoxal 5′-phosphate (PLP)-dependent enzymes ...
Vitalia V. Kulikova +6 more
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Frontiers in Chemistry, 2021 Chiral sulfoxides are valuable organosulfur compounds that have been widely used in medicinal and organic synthesis. Biocatalytic approaches for preparing chiral sulfoxides were developed in the past few years, mainly through asymmetric oxidation of ...
Tao Peng +4 more
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Research progress on metabolic pathway of S-alk(en)ylcysteine sulfoxides in Allium
Guangxi Zhiwu, 2023 Allium L. is one of the largest genera of angiosperms, including garlic, onion, green Chinese onion, Chinese chive and other important vegetable crops with unique spicy flavor.
Huamin ZHANG +4 more
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Beilstein Journal of Organic Chemistry, 2021 A series of 1-heteroatom-substituted vinyl p-tolyl sulfoxides were prepared and treated with organometallic reagents to evaluate which combination of sulfoxides and organometallic reagents yielded alkynes the most efficiently.
Tsutomu Kimura +3 more
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Advance in the Synthesis of Sulfoxides and Sulfinamides from β-Sulfinyl Esters
Organics, 2023 Sulfoxides and sulfinamides play important roles in the pharmaceutical industry, organic synthesis and fine chemicals. This review will demonstrate that, under catalysis by transition metals, β-sulfinyl esters, as nucleophilic reagents, react with a ...
Xianjie Yin, Qiaoling Zhang, Qingle Zeng
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Synthesis and Preliminary Screening of the Biological Activity of Sulindac Sulfoximine Derivatives
Applied Sciences, 2023 Sulindac is a well-known anti-inflammatory agent, sometimes employed as an adjuvant in antitumor therapy. Due to the recent interest in sulfoximine for its potential chemotherapeutics, we decided to transform sulindac and its methyl ester into the ...
Cosimo Cardellicchio +6 more
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Acta Crystallographica Section E Structure Reports Online, 2010 There are two independent mol-ecules in the asymmetric unit of the title compound, C(14)H(14)OS, which have asymmetric S-C bonds [1.791 (5) and 1.804 (5) Å in one mol-ecule and 1.798 (5) and 1.804 (5) Å in the other]. The long axes of the mol-ecules are directed along the crystallographic b axis.
Hai-Yang Liu +3 more
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Molecules, 2022 A chemoselective procedure for MCPBA oxidation of 26-thiodiosgenin to corresponding sulfoxides and sulfone was elaborated. An unusual equilibration of sulfoxides in solution was observed.
Aneta M. Tomkiel +5 more
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Molecules, 2020 Testosterone plays an important role in male sexual characteristics and maturation, and decreased testosterone levels increase the risk of several diseases.
Yuya Nakayama +5 more
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Current Opinion in Chemical Biology, 2023 In the review, current status of sulfoxides on the pharmaceutical market is discussed. In the first part of the article, natural sulfoxides will be described with a special focus on sulforaphane and amanitin, a mushroom toxin which has been developed as payload in antibody drug conjugates in the possible cancer treatment.
Elżbieta Wojaczyńska +1 more
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