Results 11 to 20 of about 86,294 (392)
Acta Crystallographica Section E Structure Reports Online, 2010 There are two independent mol-ecules in the asymmetric unit of the title compound, C(14)H(14)OS, which have asymmetric S-C bonds [1.791 (5) and 1.804 (5) Å in one mol-ecule and 1.798 (5) and 1.804 (5) Å in the other]. The long axes of the mol-ecules are directed along the crystallographic b axis.
Hai-Yang Liu +3 more
openaire +3 more sources
Molecules, 2022 A chemoselective procedure for MCPBA oxidation of 26-thiodiosgenin to corresponding sulfoxides and sulfone was elaborated. An unusual equilibration of sulfoxides in solution was observed.
Aneta M. Tomkiel +5 more
doaj +1 more source
Molecules, 2020 Testosterone plays an important role in male sexual characteristics and maturation, and decreased testosterone levels increase the risk of several diseases.
Yuya Nakayama +5 more
doaj +1 more source
Trifluoromethyl Sulfoxides: Reagents for Metal‐Free C−H Trifluoromethylthiolation
Angewandte Chemie, 2020 Trifluoromethyl sulfoxides are a new class of trifluoromethylthiolating reagent. The sulfoxides engage in metal‐free C−H trifluoromethylthiolation with a range of (hetero)arenes.
Dong Wang +6 more
semanticscholar +1 more source
Current Opinion in Chemical Biology, 2023 In the review, current status of sulfoxides on the pharmaceutical market is discussed. In the first part of the article, natural sulfoxides will be described with a special focus on sulforaphane and amanitin, a mushroom toxin which has been developed as payload in antibody drug conjugates in the possible cancer treatment.
Elżbieta Wojaczyńska +1 more
openaire +2 more sources
Chemical Reviews, 2019 Organosulfur compounds have long played a vital role in organic chemistry and in the development of novel chemical structures and architectures. Prominent among these organosulfur compounds are those involving a sulfur(IV) center, which have been the ...
Daniel Kaiser +4 more
semanticscholar +1 more source
ACS Catalysis, 2020 The photocatalytic deoxygenation of sulfoxides to generate sulfides facilitated by either Ir[(dF(CF3)ppy)2(dtbbpy)]PF6 or fac-Ir(ppy)3 is reported. Mechanistic studies indicate that a radical chain mechanism operates, which proceeds via a phosphoranyl ...
Aimee K. Clarke +4 more
semanticscholar +1 more source
Enantiomeric oxidation of organic sulfides by the filamentous fungi Botrytis cinerea, Eutypa lata and Trichoderma viride [PDF]
, 2007 The biotransformations of a series of substituted sulfides were carried out with the filamentous fungi Botrytis cinerea, Eutypa lata and Trichoderma viride.
Annunziata +28 more
core +2 more sources
Electrochemistry Communications, 2019 A highly efficient chemo-selective electrochemical oxidation of thioethers to sulfoxides and sulfones was developed. The hydrogen bonding network generated from hexafluoro-2-propanol (HFIP) and acetic acid (AcOH) plays an important role in the modulation
Shiwen Liu +6 more
doaj +1 more source
Can acyclic conformational control be achieved via a sulfur-fluorine gauche effect? [PDF]
, 2015 The gauche conformation of the 1,2-difluoroethane motif is known to involve stabilising hyperconjugative interactions between donor (bonding, σC-H) and acceptor (antibonding, σ*C-F) orbitals.
Daniliuc, C +4 more
core +1 more source