Results 81 to 90 of about 51,515 (263)

Understanding protein–flavor interactions: Factors, characterization techniques, and the effect of processing

open access: yesFood Biomacromolecules, EarlyView.
Abstract The perception of flavor in a food system depends on its release from the protein matrix. Apart from hydrogen bonding, hydrophobic interactions and van der Waal's forces, the formation of covalent adducts between the flavor and protein highly impacts the release of flavor from the protein matrix.
Arshita Verma   +2 more
wiley   +1 more source

Crystal structure and Hirshfeld surface analysis of dimethyl 3-methyl-8-{[4-(trifluoromethyl)phenyl]sulfonyl}-7,8-dihydro-4H-4,6a-epoxybenzo[b]naphtho[1,8-de]azepine-5,6-dicarboxylate

open access: yesActa Crystallographica Section E: Crystallographic Communications
The molecular conformation of the title compound, C29H22F3NO7S, is stable due to the intramolecular C—H...O hydrogen bonds. The central seven-membered ring adopts a distorted chair form.
Gleb M. Burkin   +6 more
doaj   +1 more source

Screening anticancer peptides performance in organotypic prostate tumor‐stroma 3D models

open access: yesInternational Journal of Cancer, EarlyView.
What's New? Peptide‐based drugs have emerged as promising anticancer therapies for their potential to disrupt protein–protein interactions. In this study, the authors developed a physiomimetic human 3D prostate cancer spheroid model to assess the efficacy of the CAVPENET peptide in inhibiting tumor growth. Upon incubation with CAVPENET, prostate cancer
Bárbara Matos   +7 more
wiley   +1 more source

Probing Metal Tip‐Induced Bond Weakening of a Reactive Alkyne Center Aligned via a Rigid Triphenylmethane‐Based Tripod on Au(111) by TERS and DFT

open access: yesJournal of Raman Spectroscopy, EarlyView.
We investigate tip‐induced bond weakening of a single alkyne center immobilized and aligned upright on Au(111) using a rigid triphenylmethane‐based tripod. By varying the tip–molecule distance, we observe shifts in the ≡C–H and –C≡C– vibrational bands via ultrahigh vacuum low‐temperature tip‐enhanced Raman scattering (TERS).
Gang Li   +12 more
wiley   +1 more source

Mechanophoric 3‐Arm Star Functional Block Copolymer Based on Rhodamine Derivative

open access: yesMacromolecular Materials and Engineering, EarlyView.
Mechanoresponsive rhodamine containing linear and star block and random copolymers were synthesized and characterized. All materials transitioned into a “switch‐on” state in the film form, but only the star block copolymer architecture exhibited a complete and precise peak shift upon stretching, providing new insights into the mechanochemical ...
Swadhin Chakraborty   +8 more
wiley   +1 more source

Fatty Acylation of Phospholipase D1 on Cysteine Residues 240 and 241 Determines Localization on Intracellular Membranes [PDF]

open access: hybrid, 1999
Jane M. Sugars   +4 more
openalex   +1 more source

Poly(sarcosine) Lipid Synthesis From CO2‐Based Sarcosine‐N‐Carboxyanhydride

open access: yesMacromolecular Rapid Communications, EarlyView.
In this work, we optimize and scale‐up a CO2‐based synthesis of sarcosine‐N‐carboxyanhydride (Sar‐NCA) to the gram scale. The low toxicity and simplicity of the approach make it an attractive alternative to current toxic phosgene‐based approaches. The CO2‐based Sar‐NCA has sufficient purity for controlled polymerization.
Florian T. Kaps   +7 more
wiley   +1 more source

acylals

open access: yes, 2014
Citation: 'acylals' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.A00119 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms. Requests for commercial usage
openaire   +1 more source

Rapid Epoxy Polymerization Induced by Aliphatic Cyclic Tertiary Amines: The Roles of Nucleophilicity and Leaving Ability

open access: yesMacromolecular Rapid Communications, EarlyView.
Quinuclidine, as a tertiary amine, can rapidly polymerize epoxy groups. We investigated the relationship between amine properties and polymerization behavior by monitoring the reactions of various tertiary amines with epoxy groups. The results indicate that quinuclidine, the most nucleophilic amine examined, promotes epoxy polymerization.
Yukai Ito, Daisuke Aoki, Koji Arimitsu
wiley   +1 more source

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