Results 131 to 140 of about 153,292 (304)
Interaction of some extreme-pressure type lubricating compounds with an iron surface [PDF]
An iron surface was exposed to the extreme-pressure type lubricant benzyl chloride, dichlorophenyl phosphine, dichlorophenyl phosphine sulfide, ophenyl phosphine oxide.
Buckley, D. H.
core +1 more source
Expanding the Chemical Space of Cyclic Polyphthalaldehyde via Post‐Functionalization
In this work, we developed a post‐functionalization approach to achieve water‐soluble cyclic polyphthalaldehyde (cPPA) polymers via click chemistry. ABSTRACT Cyclic polyphthalaldehydes (cPPAs) are hydrophobic cyclic polymers with stimuli‐responsive depolymerization property. The introduction of hydrophilic functionalities to cPPAs is challenging due to
Liting He +5 more
wiley +1 more source
A polymer‐intercalated modulation assembly strategy was proposed to synthesize mesoporous single‐crystalline BiVO4 with tunable pore structure by co‐assembly of inorganic–organic composite through coordination bonds and hydrogen bonds. Thanks to single‐crystalline properties and mesoporous structure with vanadium vacancy microenvironment, the prepared ...
Wei Li +6 more
wiley +1 more source
The restrained side‐chain accessibility and versatility of GNRs extremely impede their multifunctionality, solution processability, and numerous solution‐based applications. We report herein a robust liquid‐phase bottom‐up synthesis approach for high‐efficiency preparation of side‐chain sequence‐regulated functional GNRs.
Baiyang Chen +8 more
wiley +1 more source
Electrochemical Nitrate Reduction Reaction to Ammonia at Industrial‐Level Current Densities
This review starts from the mechanism and theoretical basis of electrochemical nitrate reduction reaction (NO3−RR), and systematically summarizes and discusses the design strategies of industrial‐level current density catalysts. In addition, the progress of industrial‐level NO3−RR‐based electrolyzers, including flow reactor and membrane electrode ...
Zhijie Cui +4 more
wiley +1 more source
A Noncovalent Click‐to‐Release Strategy to Control Bond Cleavage and Prodrug Activation
Extending the click‐to‐release concept beyond covalent ligation, we introduce a noncovalent click‐to‐release strategy based on cucurbituril‐adamantane (CB‐Ad) association. A supramolecular preassembly encapsulating a self‐immolative guest (SIG) is rationally designed to prevent premature release, while adding a high‐affinity Ad guest initiates the CB ...
Xuancheng Fu +9 more
wiley +2 more sources
Reductive Benzylation of Aromatic Nitro Compounds by Means of Benzyl Alcohol.
S, Miyano, N, Abe, A, Uno
openaire +3 more sources
Multiple H-Rearrangements in 10-Benzylthio-dithranol Radical Cations [PDF]
10-Alkylthio- and 10-arylthio-derivatives of dithranol (anthralin; 1,8-dihydroxy-9-anthrone) are of interest in search for new anti-psoriatic agents2 , 3 ).
Huang, H. S. +2 more
core
Difluoromethyl (CF2H) group, the bioisostere of hydroxyl thiol methyl or amide is privileged in medicinal chemistry due to hydrogen‐binding ability and lipophilic, metabolically stable, and chemical inert nature. However, enatioseleceive CF2H introduction remains challenging.
Peng Liu +9 more
wiley +1 more source
(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh +5 more
wiley +2 more sources

