Results 31 to 40 of about 83,738 (273)
Nature Communications, 2018 Catalytic enantioselective synthesis of trifluoromethylthiolated molecules remains a challenge. Here, the authors report a bifunctional selenide-catalyzed approach for the synthesis of structurally complex chiral trifluoromethylthiolated ...
Jie Luo +3 more
doaj +1 more source
Enantioselective Synthesis of 5-epi-Citreoviral Using Ruthenium-Catalyzed Asymmetric Ring-Closing Metathesis [PDF]
, 2009 Chiral ruthenium olefin metathesis catalysts can perform asymmetric ring-closing reactions in ≥90% ee with low catalyst loadings. To illustrate the practicality of these reactions and the products they form, an enantioselective total synthesis of 5-epi ...
Funk, Timothy W.
core +2 more sources
Beilstein Journal of Organic ChemistryThe desymmetric enantioselective reduction of cyclic 1,3-dicarbonyl compounds is a powerful tool for the construction of ring systems bearing multiple stereocenters including all-carbon quaternary stereocenters, which are widely useful chiral building ...
Dong-Xing Tan, Fu-She Han
doaj +1 more source
Enantioselective nickel-catalyzed dicarbofunctionalization of 3,3,3-trifluoropropene
Nature Communications, 2022 Strategies for the catalytic asymmetric synthesis of trifluoromethylated compounds remain scarce. Here, the authors report the nickel-catalyzed enantioselective dicarbofunctionalization of 3,3,3-trifluoropropene.
Yun-Ze Li +5 more
doaj +1 more source
Modern Synthetic Strategies with Organoselenium Reagents: A Focus on Vinyl Selenones
Molecules, 2021 In recent years, vinyl selenones were rediscovered as useful building blocks for new synthetic transformations. This review will highlight these advances in the field of multiple-bond-forming reactions, one-pot synthesis of carbo- and heterocycles ...
Martina Palomba +3 more
doaj +1 more source
Synthesis and Crystal Structure of 1-(3-fluorophenyl)-3-(3,4,5-trimethoxybenzoyl)thiourea [PDF]
, 2011 The title thiourea was synthesized by reaction of 3,4,5-trimethoxybenzoyl isothiocyante with 3-fluoroaniline. The 3,4,5-trimethoxybenzoyl isothiocyante was produced in situ by reaction of 3,4,5-trimethoxybenzoyl chloride with ammonium thiocyanate in dry ...
Bolte, Michael +2 more
core +2 more sources
Advanced Functional Materials, EarlyView.The SERS spectra of reporter molecules adsorbed on chiral gold nanorods depends on the handedness of circularly polarized light (CPL‐SERS). The bisignate plasmonic CD spectra of chiral nanorods provides wavelength‐dependent CPL‐SERS. Selective discrimination of chiral nanorod handedness and different Raman reporters allow highly sensitive codification ...
Andrés Serrano‐Freijeiro +9 more
wiley +1 more source
Asymmetric total synthesis of yuzurimine-type Daphniphyllum alkaloid (+)-caldaphnidine J
Nature Communications, 2020 Despite being known for more than 50 years, yuzurimine-type alkaloids have not been accessed by total synthesis. Here, the authors report the first enantioselective total synthesis of (+)-Caldaphnidine J, a highly complex yuzurimine-type Daphniphyllum ...
Lian-Dong Guo +6 more
doaj +1 more source
All‐Inorganic InP/ZnSe/ZnS Quantum Dots with Chalcogenidometallate Ligands for Biosolar Catalysis
Advanced Functional Materials, EarlyView.Intrinsic charge transfer limitations in core/shell QDs are addressed through a ligand‐induced band offset engineering (LBOE) strategy utilizing metal chalcogenide complex (MCC) ligands. The MCC‐functionalized InP/ZnSe/ZnS QDs exhibited remarkably augmented hydrogen peroxide (H2O2) generation.
Jaehwan Lee +10 more
wiley +1 more source
Nature CommunicationsDeveloping facile and direct synthesis routes for enantioselective construction of cyclic π-conjugated molecules is crucial. However, originate chirality from the distorted structure around heptagon-containing polyarenes is largely overlooked, the ...
Huan Zhang +5 more
doaj +1 more source