The Amide Group as Modulator of Crystalline and Liquid Crystalline Structures in Isocyano-alkylanilide Silver (I) Complexes [PDF]
, 2015 Producción CientíficaSilver(I) complexes [AgX(CNR] and [Ag(CNR)2]X (X = anionic ligand), containing an amide-functionalized isocyanide, CNR = CN-C6H4-NHCOR, have been synthesized and their X-ray structures have been determined for [Ag(X)(CN-C6H4-NHCOCH3)]
Baena Alonso, María Jesús +2 more
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Amide-Stabilized Enols in the Enol-Ugi Reaction: A Five-Component Synthesis of Triamides
Chemistry Proceedings, 2021 In continuation with our research in the use of enols in multicomponent reactions with isocyanides (IMCR), for the first time we have used amide-stabilized enols as the acid component in enol-Ugi reactions.
Ana G. Neo +3 more
doaj +1 more source
Angewandte Chemie, EarlyView.RhI dimers with bridging aryl isocyanide and di‐phosphine ligands show NIR‐I or NIR‐II fluorescence/phosphorescence, depending on the ligands and conformational rigidity at the Rh2 core. Rh‐Rh interactions can be tuned by peripheral modification of the aryl isocyanide ligand, resulting in a rigid Rh2 core and improved photophysical properties ...
Vanitha R. Naina +4 more
wiley +2 more sources
Koordinationschemie Perhalogenierter Cyclopentadine und Alkine, XV [PDF]
, 1993 Coordination Chemistry of Perhalogenated Cyclopentadienes and Alkynes, XV[1]. - Systematic Generation of Fivefold Ring-Silylated Cyclopentadienyl Manganese Complexes from [C5Br5]Mn(CO)3.
Blake +12 more
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Angewandte Chemie, EarlyView.This work details the rapid generation (t ≤ 5 min) of size‐tunable, ultralow dispersity (Ð ≤ 1.01) 2D hexagonal nanosheets by self‐limiting polymerization‐induced crystallization‐driven self‐assembly (SL‐PI‐CDSA) of modular and templating poly(aryl isocyanide) block copolymers, with functions that permit post‐polymerization modifications. Specifically,
Randall A. Scanga +13 more
wiley +2 more sources
Reactivity of the dinuclear fulvalene cyclopentadienyl zirconium cationic species \ud [{Zr(η5-C5H5)}2(μ-CH2)(μ-Cl)(μ-η5-C5H4-η5-C5H4)]+ with isocyanides and carbon monoxide: insertion reactions, spectroscopic characterization and synthetic aspects [PDF]
, 2001 The dinuclear cationic zirconium compound [{Zr(η5-C5H5)}2(μ-CH2)(μ-Cl)(μ-η5-C5H4-η5-C5H4)][BMe(C6F5)3] 1 reacts in dichloromethane at −78 °C with three equivalents of RNC (R=tBu, 2,6-Me2C6H3) via insertion into the Zr-μ-methylene bond to give the new ...
Cuenca Agreda, Tomás +3 more
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Medicinal Chemistry of Isocyanides [PDF]
Chemical Reviews, 2021 In eons of evolution, isocyanides carved out a niche in the ecological systems probably thanks to their metal coordinating properties. In 1859 the first isocyanide was synthesized by humans and in 1950 the first natural isocyanide was discovered. Now, at the beginning of XXI century, hundreds of isocyanides have been isolated both in prokaryotes and ...
Alberto Massarotti +4 more
openaire +4 more sources
Xanthate Based Radical Cascade Toward Multicomponent Formation of Pyrrolopyrimidines
Molecules, 2011 A short sequential synthesis of pyrrolidino- pyridines and pyrimidines illustrates the potential of combining Ugi-Smiles couplings with radical tin-free processes.
Patil Pravin +2 more
doaj +1 more source
Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes [PDF]
, 2018 Isocyanides insert into gold(III)-hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by ...
Bochmann, Manfred +5 more
core +1 more source
Selectivity in multiple multicomponent reactions: types and synthetic applications
Beilstein Journal of Organic Chemistry, 2019 Multiple multicomponent reactions reach an unparalleled level of connectivity, leading to highly complex adducts. Usually, only one type of transformation involving the same set of reactants takes place.
Ouldouz Ghashghaei +2 more
doaj +1 more source