Results 41 to 50 of about 8,383 (210)
Catalysis direction selective asymmetric polymerization in chiral liquid crystal medium [PDF]
, 2014 A series of optically inactive aryl isocyanide derivatives were polymerized with an achiral nickel catalyst (Ni(II)Cl2) in a cholesteric liquid crystal (CLC) medium.
Goto Hiromasa +4 more
core +1 more source
Palladium(II)-Mediated Addition of Benzenediamines to Isocyanides: Generation of Three Types of Diaminocarbene Ligands Depending on the Isomeric Structure of the Nucleophile [PDF]
, 2016 Coupling of the palladium-bis(isocyanide) complexes cis-[PdCl2(CNR)2] (R = 2,6-Me2C6H3 1, 2-Cl-6-MeC6H3 2) with benzene-1,3-diamine (BDA1) leads to the diaminocarbene species cis-[PdCl2(CNR){C(NHR)NH(1,3-C6H4NH2)}] (5 and 6, respectively).
Boyarskiy, Vadim P +6 more
core +8 more sources
Molecules, 2019 A novel one-pot multicomponent reaction to synthesize substituted imidazopyrazines is described. In brief, 1H-(imidazol-5-yl)-N-substituted methanamines react with aldehydes and isocyanides in methanol at room temperature to give imidazopyrazine ...
Ubaldina Galli +7 more
doaj +1 more source
Crystals, 2021 The isocyanide complexes cis-[MCl2(CNC6H4-4-X)2] (M = Pd; X = Cl, Br; M = Pt; X = Br) form isomorphous crystal structures exhibiting the Cl/Br and Pd/Pt exchanges featuring 1D chains upon crystallisation.
Maria V. Kashina +2 more
doaj +1 more source
Metal-only Lewis pairs between group 10 metals and Tl(I) or Ag(I): insights into the electronic consequences of Z-type ligand binding† [PDF]
, 2015 Complexes bearing electron rich transition metal centers, especially those displaying coordinative unsaturation, are well-suited to form reverse-dative σ-interactions with Lewis acids.
Barnett, Brandon R. +6 more
core +3 more sources
Beilstein Journal of Organic Chemistry, 2019 A new multicomponent reaction has been developed between isocyanides, sulfur and alcohols or thiols under mild reaction conditions to afford O-thiocarbamates and dithiocarbamates in moderate to good yields.
András György Németh +2 more
doaj +1 more source
Reaction between Indazole and Pd-Bound Isocyanides—A Theoretical Mechanistic Study
Molecules, 2018 The mechanism of the addition of indazole (Ind)—a bifunctional aromatic N,NH-nucleophile—to cyclohexyl isocyanide coordinated to the palladium(II) center in the model complex cis-[PdCl2(CNMe)(CNCy)] (1) to give the corresponding aminocarbene ...
Girolamo Casella +3 more
doaj +1 more source
Beilstein Journal of Organic Chemistry, 2020 An unexpected formation of carbamothioates by a sodium hydride-mediated reaction of arylmethyl isocyanides with xanthate esters in DMF is reported. The products thus obtained were compared with the carbamothioates obtained by the sodium hydride-mediated ...
Narasimhamurthy Rajeev +10 more
doaj +1 more source
Urea Synthesis from Isocyanides and O-Benzoyl Hydroxylamines Catalyzed by a Copper Salt
Molecules, 2022 In the presence of CuOAc, a series of unsymmetric ureas can be generated in moderate to good yields under mild reaction conditions (10 mol% of CuOAc, 2 equiv t-BuONa or PhONa, 30 °C), using aryl isocyanides and O-benzoyl hydroxylamines as the readily ...
Ning Yu +5 more
doaj +1 more source
Mitochondria as a Potential Antifungal Target for Isocyanide Compounds [PDF]
, 2020 The discovery of antibiotics and antifungals greatly impacted medicine and human health, allowing the effective treatment of infections that were previously deadly. However, due to routine and sometimes excessive usage of these compounds, the development
Berkowitz, David +5 more
core +1 more source