Highly fluorescent complexes with 3-isocyanoperylene and N-(2,5-di-tert-butylphenyl)-9-isocyano-perylene- 3,4-dicarboximide [PDF]
, 2014 Producción CientíficaThe perylene derivatives 3-isocyanoperylene (Per–N≡C) (4a) and N-(2,5-di-tert-butylphenyl)- 9-isocyano-perylene-3,4-dicarboximide (PMI–N≡C) (4b) were prepared and used to synthesize gold complexes [AuX(CNR)] (X = C6F5 (5a,b), C6F4 ...
Aullón, Gabriel +4 more
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Molecules, 2022 A new approach for the synthesis of 2-aminobenzofurans has been described via Sc(OTf)3 mediated formal cycloaddition of isocyanides with the in situ generated ortho-quinone methides (o-QMs) from o-hydroxybenzhydryl alcohol. Notably, as a class of readily
Huaxin Lin +6 more
doaj +1 more source
Utjecaj izloženosti 1,6-heksametilen diizocijanatu (HDI) na vršni ekspiratorni protok u autolakirera u Iranu [PDF]
, 2010 The aim of this study was to investigate the effects of occupational exposure to 1,6-hexamethylene diisocyanate (HDI) on peak flowmetry in automobile body paint shop workers in Iran.
A. Musk +24 more
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Synthesis of N-7-Substituted Purines from Imidazole Precursors
Molecules, 1999 Synthesis of purines and purine mono-1-oxides from the respective 5-substituted 4-nitroimidazole derivatives is described. The commercially available 4-nitroimidazole, in a few simple steps (including Vicarious Nucleophilic Substitution of Hydrogen), was
Stanislaw Ostrowski
doaj +1 more source
One-step synthesis of imidazoles from Asmic (anisylsulfanylmethyl isocyanide)
Beilstein Journal of Organic Chemistry, 2021 Substituted imidazoles are readily prepared by condensing the versatile isocyanide Asmic, anisylsulfanylmethylisocyanide, with nitrogenous π-electrophiles.
Louis G. Mueller +3 more
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The Chemistry of Phenylimidotechnetium(V) Complexes with Isocyanides: Steric and Electronic Factors
Molecules, 2022 Organometallic approaches are of ongoing interest for the development of novel functional 99mTc radiopharmaceuticals, while the basic organotechnetium chemistry seems frequently to be little explored. Thus, structural and reactivity studies with the long-
Guilhem Claude +5 more
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Complementary regioselectivity in the synthesis of iminohydantoins: remarkable effect of amide substitution on the cyclization [PDF]
, 2013 Complementary regioselective synthesis of iminohydantoins from isocyanoacetamides controlled by the substituent on the amide group has been described.
García Valverde, María +5 more
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Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex
Crystals, 2022 Gold(I) isocyanide complexes featuring Au···Au interactions attract considerable attention because of their tunable photophysical properties. Although the synthetic exploration of isocyanide gold(I) complexes seems reasonable, their structural diversity ...
Mariya V. Grudova +6 more
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Insertion of isocyanides into zirconium-alkyl bonds of di-ansa-zirconocene complexes. X-ray molecular structure of [Zr{(SiMe2)2(η5-C5H3))Cl(η2-C(i-Pr)N(2,6-Me2C6H3)}] [PDF]
, 1997 New dicyclopentadienyl iminoacyl zirconium complexes have been prepared and characterized by NMR spectroscopy. The reaction of [Zr{SiMe2)2(η5-C5H3)2)Me2] with CNR (R 2,6-Me2C6H3, t-Bu) yields [Zr((SiMe2)2(η5-C5H3)2Me(η2-CMeNR)] (R = 2,6-Me2C6H3, t-Bu),
Barriola, Antonio M. +6 more
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European Journal of Medicinal Chemistry ReportsThe reaction of dehydroabiethylamine (DHA) with isocyanides and formaldehyde produces varying products depending on the conditions employed. In a 4-component Ugi reaction using benzyl isocyanide, paraformaldehyde, and TMS-azide, the anticipated tetrazole
Niels V. Heise +3 more
doaj +1 more source