Results 61 to 70 of about 4,726 (220)

Oxazole Synthesis from Isocyanides

open access: yes, 2012
International audienceA new synthetic path toward oxazoles starting from isocyanides is presented. This two-step oxazole preparation involves a bromination-cyclization followed by a Suzuki cross-coupling.
Patil, Pravin   +2 more
core   +1 more source

Design, Synthesis, and Photophysical Studies of Functionalized Polyaromatic Isonitriles as Visible Light Photoredox Catalysts

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A new series of structurally rich polyaromatic isonitriles is presented as photoredox catalysts. Their photophysical properties are investigated by UV–Vis absorption and fluorescence measurements, combined with experimental and theoretical studies to evaluate both ground‐ and excited‐state redox properties.
Cristina Martini   +9 more
wiley   +1 more source

Tetrasubstituted Imidazolium Salts as Potent Antiparasitic Agents against African and American Trypanosomiases

open access: yesMolecules, 2018
Imidazolium salts are privileged compounds in organic chemistry, and have valuable biological properties. Recent studies show that symmetric imidazolium salts with bulky moieties can display antiparasitic activity against T. cruzi.
Ouldouz Ghashghaei   +8 more
doaj   +1 more source

Poly(O‐Propargyl‐N‐Amino Carbamate), a Reactive Polymer to Underpin Biomedical Applications of Poly(acetylene)s

open access: yesMacromolecular Rapid Communications, EarlyView.
We report here a new methodology to prepare functional poly(acetylene)s under aqueous conditions. This methodology is underpinned by poly(O‐propargyl‐N‐amino carbamate) (P1), a reactive poly(acetylene) carrying acyl hydrazines. Thus, P1 reacts with aldehydes to give functional poly(acetylene)s, including cationic, hydrophobic, and sugar‐loaded poly ...
Tom Leigh   +8 more
wiley   +1 more source

Nickel-Catalyzed Formal Aminocarbonylation of Unactivated Alkyl Iodides with Isocyanides

open access: yes, 2020
Herein, we disclose a Ni-catalyzed formal aminocarbonylation of primary and secondary unactivated aliphatic iodides with isocyanides to afford alkyl amide, which proceeds via the selective monomigratory insertion of isocyanides with alkyl iodides ...
Yifeng Chen (1412560)   +5 more
core   +2 more sources

Three-Component Reactions of 3-Arylidene-3H-Indolium Salts, Isocyanides and Amines

open access: yesMolecules, 2021
A multicomponent reaction of isocyanides with aryl(indol-3-yl)methylium salts and amines has been found. A series of aryl(indol-3-yl)acetimidamides was obtained in up to 96% yields.
Hung M. Nguyen   +4 more
doaj   +1 more source

1,1‐and 1,2‐Diborylalkenes: Preparation and Synthetic Applications

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 12, 17 June 2026.
In this review, we highlight recent advances in the synthesis and reactivity of 1,1‐diborylalkenes and 1,2‐diborylalkenes, along with various transformations leading to C‐C, C‐heteroatom, and multicomponent products. By providing a comprehensive and practical resource, this review aims to assist researchers in exploring the synthetic utility of 1,1 and
Jayaram Vankudoth   +2 more
wiley   +1 more source

POLYMERIC ISOCYANIDES - SYNTHESIS, PROPERTIES AND APPLICATIONS

open access: yes, 1993
A general review of polymeric isonitriles (polymeric isocyanides or isocyano polymers) is presented, drawing attention to a fascinating class of reactive polymers for basic research and several potential applications.
CORAIN, BENEDETTO   +2 more
core   +1 more source

First Homoleptic Isocyanides of Niobium and Tantalum1

open access: yes, 2016
First Homoleptic Isocyanides of Niobium and ...
John E. Ellis (2053192)   +2 more
core   +2 more sources

Rh(III)‐Catalyzed [4+2] Annulation of Imidazoles With α‐Diazocarbonyl Compounds: Direct Access to π‐Conjugated Imidazole‐Fused Isoquinolinone

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 23, 16 June 2026.
A Rh(III)‐catalyzed [4 + 2] annulation of 2‐aryl imidazoles/benzimidazoles with α‐diazocarbonyl compounds is developed for the synthesis of π‐conjugated imidazo/benzimidazo[2,1‐a]isoquinolinones systems. Mechanistic studies and control experiment reveal that the reaction proceeds via imidazole‐directed ortho C(sp2)–H activation, followed by carbene C–H
Ganesh P. Pawar   +4 more
wiley   +1 more source

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