Results 11 to 20 of about 5,182 (207)

Isocyanides as a Chemical Tool for Identifying [Fe]-Hydrogenase-Dependent Methanogenesis. [PDF]

open access: yesChembiochem
In model methanogens, [Fe]‐hydrogenase (Hmd) substitutes nickel‐dependent hydrogenases under nickel‐limited conditions. We determined the inhibitory effects of the Hmd inhibitor, isocyanides, on methanogenesis in a cell extract and in a cell suspension.
Nomura S, Shima S.
europepmc   +2 more sources

Visible light-driven dearomatization of tryptamine-derived isocyanides through aggregation-based charge transfer [PDF]

open access: yes, 2023
Aggregation-based charge transfer has emerged as an attractive concept in organic chemistry. In this work, we have demonstrated the ability of tryptamine-derived isocyanides to form aggregates, which enable a single electron transfer step to generate ...
Minghui , Wu   +7 more
core   +2 more sources

PHOTOCHEMICAL OXIDATION AND ISOMERIZATION OF ISOCYANIDES.

open access: yes, 1973
PHOTOCHEMICAL OXIDATION AND ISOMERIZATION OF ...
ANTHONY JACOB JR. SPAK (7964411)
core   +6 more sources

Multicomponent Cyclopolymerization of Alkynes, Isocyanides and Isocyanates Toward Heterocyclic Polymers [PDF]

open access: yes, 2021
Multicomponent cyclopolymerization (MCCP) based on isocyanides, among the tremendous synthetic methodologies, is a powerful tool for the preparation of functional heterocyclic polymers like poly(maleimide)s (PMDs), which should be further developed.
Baixue, Li   +5 more
core   +2 more sources

Ugi Reaction on α-Phosphorated Ketimines for the Synthesis of Tetrasubstituted α-Aminophosphonates and Their Applications as Antiproliferative Agents

open access: yesMolecules, 2021
An Ugi three-component reaction using preformed α-phosphorated N-tosyl ketimines with different isocyanides in the presence of a carboxylic acid affords tetrasubstituted α-aminophosphonates.
Adrián López-Francés   +4 more
doaj   +1 more source

Using highly substituted isocyanides in the synthesis ofiminothiophenes fused to quinolines [PDF]

open access: yesشیمی کاربردی روز, 2018
In this manuscript the reaction of 2-mercaptoquinoline-3-carbaldehydes and 1,1,3,3-tetramethyl butylisocyanide as highly substituted isocyanide in the reflux of ethanol without catalyst is described.
Morteza Shiri   +3 more
doaj   +1 more source

Synthesis of Depsipeptides via Isocyanide-Based Consecutive Bargellini–Passerini Multicomponent Reactions

open access: yesSynOpen, 2021
An efficient and straightforward approach has been established for the preparation of a new class of depsipeptide structures via isocyanide-based consecutive Bargellini–Passerini multicomponent reactions.
Hassan Farhid   +3 more
doaj   +1 more source

Amide-Stabilized Enols in the Enol-Ugi Reaction: A Five-Component Synthesis of Triamides

open access: yesChemistry Proceedings, 2021
In continuation with our research in the use of enols in multicomponent reactions with isocyanides (IMCR), for the first time we have used amide-stabilized enols as the acid component in enol-Ugi reactions.
Ana G. Neo   +3 more
doaj   +1 more source

Silver-Catalyzed Decarboxylative Acylation of Isocyanides Accesses to α-Ketoamides with Air as a Sole Oxidant

open access: yesMolecules, 2023
α-Ketoamide moieties, as privileged units, may represent a valuable option to develop compounds with favorable biological activities, such as low toxicity, promising PK and drug-like properties.
Jia Xu   +6 more
doaj   +1 more source

Sulfonyl isocyanides RSO2NC [PDF]

open access: yes, 2017
Flash vacuum pyrolysis (FVP) of 5-azido-1-aryltetrazoles results in triple N2 elimination and formation of aryl isocyanides RNC, which rearrange in part to aroylnitriles RCN under the reaction conditions.
Horst, Briehl, Curt, Wentrup
core   +1 more source

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