Results 51 to 60 of about 20,504 (258)

Cobalt Single‐Atom‐Bonded Covalent Heptazine Framework Selectively Generates Nonradicals in Fenton‐Like Catalysis for Rapidly Purifying Organic Wastewater

open access: yesEcoEnergy, EarlyView.
Cobalt single‐atom‐bonded covalent heptazine framework activates peroxymonosulfate to generate 1O2, with the concurrent formation of CoO2+, for wastewater treatment. ABSTRACT Engineering the coordination architecture of cobalt single‐atom catalysts (Co‐SACs) represents a promising strategy to activate peroxymonosulfate (PMS) for sewage purification. In
Yuhang Deng   +6 more
wiley   +1 more source

Synthesis of highly substituted allenylsilanes by alkylidenation of silylketenes [PDF]

open access: yes, 2005
BACKGROUND: Allenylsilanes are useful intermediates in organic synthesis. An attractive, convergent but little used approach for their synthesis is the alkylidenation of stable silylketenes.
Ducept, P.C., Marsden, S.P.
core   +3 more sources

3-Benzoylisoxazolines by 1,3-Dipolar Cycloaddition: Chloramine-T-Catalyzed Condensation of α-Nitroketones with Dipolarophiles

open access: yesMolecules, 2021
In this study, 3-benzoylisoxazolines were synthesized by reacting alkenes with various α-nitroketones using chloramine-T as the base. The scope of α-nitroketones and alkenes is extensive, including different alkenes and alkynes to form various ...
Xinhui Pan   +8 more
doaj   +1 more source

Synthesis of Novel BINOL Analogs: 3,3′‐Dicarbonyl‐1,1′‐binaphthyl‐4,4′‐diols as Precursors to the Uncharted 5,5′‐Binaphtho[2,1‐d]isoxazole

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The parent 5,5′‐binaphtho[2,1‐d]isoxazole and its 3,3′‐dimethyl and 3,3′‐diphenyl derivatives are synthesized via condensation of the respective dicarbonyl compounds with hydroxylamine, followed by cyclodehydration of the resulting dioximes. The dicarbonyl precursors are obtained through 4‐ or 6‐step sequences from 1‐naphthol or 1‐naphthaldehyde ...
Marek Surowiec   +6 more
wiley   +1 more source

Deep Eutectic Solvents: The Organic Reaction Medium of the Century [PDF]

open access: yes, 2016
This microreview summarizes the use of deep eutectic solvents (DESs) and related melts in organic synthesis. Solvents of this type combine the great advantages of other proposed environmentally benign alternative solvents, such as low toxicity, high ...
Abbott   +192 more
core   +2 more sources

A “One‐Pot” Metal‐Free Synthesis and Evaluation of Antiproliferative Activity of Diversely Functionalized Pyrrolidine‐2‐Ones

open access: yesJournal of Heterocyclic Chemistry, EarlyView.
A new “one‐pot” metal‐free stereoselective method for the synthesis of novel diversely functionalized pyrrolidine‐2‐ones from N‐alkyl‐ or N‐arylsulfonamidoacetophenones was developed. The majority of obtained compounds possess low micromolar antiproliferative activities.
Samuel Dick   +7 more
wiley   +1 more source

Gold-catalyzed [4+3]- and [4+2]-annulations of 3-en-1-ynamides with isoxazoles via novel 6π-electrocyclizations of 3-azahepta trienyl cations

open access: yesChemical Science, 2018
Gold-catalysed [4+3]- and [4+2]-annulations of 3-substituted 3-en-1-ynamides with isoxazoles were achieved with Au(i) and Au(i)/Zn(ii) catalysts respectively.
Sovan Sundar Giri, Rai‐Shung Liu
semanticscholar   +1 more source

Tolerância de híbridos de milho ao herbicida isoxaflutole Tolerance of corn hybrids to isoxaflutole

open access: yesPlanta Daninha, 2008
Objetivou-se com este trabalho avaliar a tolerância de híbridos de milho ao isoxaflutole e relacionar estudos de seletividade desse herbicida conduzidos em casa de vegetação com estudos desenvolvidos em campo.
S.D. Cavalieri   +5 more
doaj   +1 more source

The continuing significance of chiral agrochemicals

open access: yesPest Management Science, Volume 81, Issue 4, Page 1697-1716, April 2025.
In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley   +1 more source

Sintesis de isoxazoles utilizando ultrasonido, para su posterior oxidacion y medicion de actividad biologica [PDF]

open access: yes, 2008
63 p.Los isoxazoles presentan una gran cantidad de actividades biológicas entre las que se puede destacar actividad antifungica y antiagregante plaquetaria, entre otras, pero existen registros que las diferentes actividades biológicas de estos compuestos
Barrios Fuentes, Pedro   +1 more
core  

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