Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles [PDF]
ARKIVOC, 2002 4-Silylated oxazoles have been shown to undergo inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions with electron-poor alkynes to generate polysubstituted furans.
Ducept, P.C., Marsden, S.P.
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Photochemical approach to functionalized benzobicyclo[3.2.1]octene structures via fused oxazoline derivatives from 4- and 5-(o-vinylstyryl)oxazoles [PDF]
Beilstein Journal of Organic Chemistry, 2014 Novel cis/trans-4- and cis/trans-5-(2-vinylstyryl)oxazoles have been synthesized by Wittig reactions from the diphosphonium salt of α, α’-o-xylene dibromide, formaldehyde and 4- and 5-oxazolecarbaldehydes, respectively.
Božić, Simona +3 more
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Regioselective Formation of 2,5-Disubstituted Oxazoles Via Copper(I)-Catalyzed Cycloaddition of Acyl Azides and 1-Alkynes [PDF]
, 2011 The reaction of 1-alkynes with acylazides in the presence of [Tpm*,BrCu(NCMe)]BF4 (Tpm*,Br = tris(3,5-dimethyl-4-bromopyrazolyl)methane) as the catalyst provides 2,5-oxazoles in moderate to high yields.
Cano Rico, Israel +3 more
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Divergent Synthesis of C5‐Heteroatom Substituted Oxazoles [PDF]
, 2022 5‐Oxazoyl‐sulfamates have been profiled as versatile building blocks for modifications of oxazoles with various nucleophiles. The unified approach provides a diversification platform to directly access 5‐amino‐oxazoles, 5‐oxazolyl‐sulfides, and 5‐oxazoyl‐
Arndt, Hans‐Dieter +2 more
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Highly selective electrochemical hydrogenation of alkynes: Rapid construction of mechanochromic materials [PDF]
, 2019 Electrochemical hydrogenation has emerged as an environmentally benign and operationally simple alternative to traditional catalytic reduction of organic compounds.
Ge, Haibo, Li, Bijin
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Transition metal-mediated synthesis of oxazoles [PDF]
, 2014 Among the synthetic methods for the formation of the oxazole ring, transition metal-mediated protocols are the most attractive in terms of selectivity, efficiency and mildness of reaction conditions.
Bresciani, Stefano +1 more
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The rapid synthesis of oxazolines and their heterogeneous oxidation to oxazoles under flow conditions. [PDF]
, 2014 A rapid flow synthesis of oxazolines and their oxidation to the corresponding oxazoles is reported. The oxazolines are prepared at room temperature in a stereospecific manner, with inversion of stereochemistry, from β-hydroxy amides using Deoxo-Fluor ...
Battilocchio, Claudio +6 more
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Total synthesis of the cyclic dodecapeptides wewakazole and wewakazole B [PDF]
, 2017 The cyclic dodecapeptides wewakazole and wewakazole B have been synthesized by a divergent strategy via a common tris-proline containing oxazole octapeptide and two separate bisoxazole containing tetrapeptide units, followed by peptide coupling and ...
Dexter, Hannah L. +2 more
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Sir John Cornforth AC CBE FRS: his synthetic work [PDF]
, 2015 Sir John Cornforth’s work on the synthesis of cholesterol and penicillamine, on the chemistry of oxazoles, the stereochemistry of the synthesis of alkenes, the synthesis of abscisic acid and of dibenzophospholes as mimics of enzyme action, is ...
Abraham E.P. +15 more
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Intramolecular Pd(II)-Catalyzed Cyclization of Propargylamides: Straightforward Synthesis of 5-Oxazole-carbaldehydes [PDF]
, 2008 (Chemical Equation Presented) Direct synthesis of 2-substituted 5-oxazolecarbaldehydes was performed by intramolecular reaction of propargylamides through treatment with a catalytic amount of Pd(II) salts in the presence of a stoichiometric amount of ...
BECCALLI E. M +4 more
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