Results 91 to 100 of about 11,166 (254)

Determination of Stability for imines derived from carbonyl compounds by conductivity measurements

Tikrit Journal of Pure Science, 2018
The project explained for the first time, how conductivity method was used in the determination of stability of some imines derived from mother compounds 2-acetyl pyridine, 3 or 4 –hydroxy benzaldehyde, and others. The method as found, simple precise
A.S.P. Azzouz, D.B.AL-Bakzo
doaj   +1 more source

Nonthermal Plasma–Enabled Cascade N2 Activation and Electroreduction

EcoEnergy, EarlyView.
Integrating plasma‐assisted NOx synthesis with subsequent electrochemical reduction enables the sustainable synthesis of high‐value N‐containing chemicals under ambient conditions. ABSTRACT The development of sustainable nitrogen fixation technologies operating under ambient conditions is critical for reducing the energy intensity and carbon footprint ...
Shijia Li, Wei Gao, Ziyun Wang
wiley   +1 more source

Halogenated monopyridinium oximes are less effective in reactivation of phosphylated cholinesterases than bisquaternary oximes

International audienceMono-quaternary pyridinium oximes derived from K-oximes K027, K048 and K203 were designed, synthesized and evaluated for the reactivation of organophosphate-inhibited cholinesterases.
Andrys, Rudolf, Malinak, David, Kohoutova, Zuzana, Musilek, Kamil, Formanova, Marketa, Prchalova, Eliska, Derat, Etienne, Hofmanova, Tereza, Psotka, Miroslav, Knittelova, Karolina   +9 more
core   +1 more source

Multidimensional Engineering Enabling Rate‐Matched C−N Coupling for Efficient Organonitrogen Electrosynthesis

EcoEnergy, EarlyView.
This review introduces rate matching as a unifying design principle for efficient electrochemical C−N coupling and highlights multidimensional engineering of catalysts, interfaces, and reactors to synchronize the generation of carbon‐ and nitrogen‐containing intermediates, balance their surface coverages, maximize C−N bond formation, and enable ...
Kaixing Cai, Chunyang Pu, Jun Yang, Guangqin Li, Jiahui Xian   +4 more
wiley   +1 more source

Chemoselective Aldehyde and Imine Reduction by a Macrocyclic Triazole–Borane Complex Triggered by a Non‐innocent Proton–Hydride Interaction

European Journal of Organic Chemistry, EarlyView.
This work describes the study on a new recyclable reagent, based on a macrocyclic triazole–borane complex. It showed high chemoselectivity for aldehyde reduction and reductive amination over ketones. This selectivity is driven by a noncovalent hydride–proton interaction that stabilizes the transition state for aldehydes but is sterically inhibited in ...
Luca Di Marino, Artur Brotons Rufes, Rosaria Schettini, Giorgio Della Sala, Francesco De Riccardis, Chiara Costabile, Irene Izzo   +6 more
wiley   +1 more source

The Expanding Role of Diazirines in Synthetic Methodology

European Journal of Organic Chemistry, EarlyView.
Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic, Dominik Schnalzer, Marko D. Mihovilovic, Michael Schnürch   +3 more
wiley   +1 more source

Solvent Free, Microwave Assisted Conversion of Aldehydes into Nitriles and Oximes in the Presence of NH2OH·HCl and TiO2

Molecules, 2009
Aromatic aldehydes bearing electron-donating groups are easily converted into their respective nitriles using NH2OH·HCl and TiO2 under microwave irradiation, while those bearing an electron-withdrawing group give the corresponding oximes.
Lucas Villas-Boas Hoelz, Biank Tomaz Gonçalves, José Celestino Barros, Joaquim Fernando Mendes da Silva   +3 more
doaj   +1 more source

Abnormal KCC2 expression and function in a mouse model of epilepsy and tuberous sclerosis complex

Epilepsia, EarlyView.
Abstract Objective Drug‐resistant epilepsy is a common, severe manifestation of the genetic disorder tuberous sclerosis complex (TSC). Although significant mechanistic and therapeutic advances have been made in TSC, treatments for seizures remain largely ineffective.
Dongjun Guo, Lirong Han, Nicholas R. Rensing, Laura A. Jansen, Michael Wong   +4 more
wiley   +1 more source

Mechanical stability in flexible perovskite solar cells: Interface engineering and device design

FlexMat, EarlyView.
Statistics of the improvement methods for f‐PSCs. Abstract Flexible perovskite solar cells (f‐PSCs) demonstrate significant potential for application in next‐generation wearable electronic devices and photovoltaic building integration due to their high power conversion efficiency and excellent power‐to‐weight ratio. However, the inherent brittleness of
Hong‐Yi Hou, Xin‐Yi Zeng, Jian‐Xin Tang, Yan‐Qing Li   +3 more
wiley   +1 more source

Coupled Environmental Effects in Competitive Inhibition of Dynamic Hydrazone Hydrogels

Macromolecular Rapid Communications, EarlyView.
Environment Alters Competitive Inhibition of Crosslinks. Ion concentration, pH, and buffer composition govern exchange kinetics and network stability in dynamic benzyl‐hydrazone hydrogels. These factors are particularly important when utilizing small‐molecule competitors for enhanced control over gel mechanics, underscoring the need to control the ...
Sirilak Mekcham, Alexander D. Claiborne, Megan S. Rothenberg, Owen A. Lee, Elizabeth Thompson, Megan R. Hill   +5 more
wiley   +1 more source